Model for solid oxide fuel cell cathodes prepared by infiltration

A 1-dimensional model of a cathode has been developed in order to understand and predict the performance of cathodes prepared by infiltration of La0.6Sr4Co1.05O3-delta (LSC) into porous backbones of Ce0.9Gd0.1O1.95 (CGO). The model accounts for the mixed ionic and electronic conductivity of LSC, ionic conductivity of CGO, gas transport in the porous cathode, and the oxygen reduction reaction at the surface of percolated LSC. Geometrical variations are applied to reflect a changing microstructure of LSC under varying firing temperatures. Using microstructural parameters obtained from detailed scanning electron microscdpy and simulations of the measured polarization resistances, an expression for the area specific resistance (r(p)) associated with the oxygen exchange on the surface of the infiltrated LSC particles was extracted and compared with literature values. A series of microstructural parameter variations are presented and discussed with the aim of presenting specific guidelines for optimizing the microstructure of cathodes prepared by infiltration. (C) 2017 Elsevier Ltd. All rights reserved.