In Situ Chemical Oxidation of Contaminated Soil and Groundwater Using Persulfate: A Review

被引：1017
作者：
Tsitonaki, Aikaterini [1 ]
Petri, Benjamin [2 ]
Crimi, Michelle [3 ]
Mosbaek, Hans [1 ]
Siegrist, Robert L. [2 ]
Bjerg, Poul L. [1 ]
机构：
[1] Tech Univ Denmark, Dept Environm Engn, Lyngby, Denmark
[2] Colorado Sch Mines, Environm Sci & Engn Div, Golden, CO 80401 USA
[3] Clarkson Univ, Dept Biol, Potsdam, NY 13699 USA
来源：
CRITICAL REVIEWS IN ENVIRONMENTAL SCIENCE AND TECHNOLOGY | 2010年 / 40卷 / 01期
关键词：
remediation; aquifer; activation; sulfate radical; oxidation; HYDROGEN ABSTRACTION REACTIONS; HEAT-ACTIVATED PERSULFATE; RATE CONSTANTS; SODIUM PERSULFATE; ORGANIC-MATTER; KINETICS; DECOMPOSITION; MECHANISM; TRICHLOROETHYLENE; SO4;
D O I：
10.1080/10643380802039303
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Persulfate is the newest oxidant that is being used for in situ chemical oxidation (ISCO) in the remediation of soil and groundwater. In this review, the fundamental reactions and governing factors of persulfate relevant to ISCO are discussed. The latest experiences for ISCO with persulfate are presented, with a focus on the different activation methods, the amenable contaminants, and the reactions of persulfate with porous media, based primarily on a critical review of the peer-reviewed scientific literature and to a lesser extent on non-reviewed professional journals and conference proceedings. The last sections are devoted to identifying the best practices based on current experience and suggesting the direction of future research.
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页码：55 / 91
页数：37
相关论文
共 80 条
[1]  
ABRANOVIC DJ, 2006, P 5 INT C REM CHLOR
[2]   CHLORIDE INTERFACE IN THE ANALYSIS OF DISSOLVED ORGANIC-CARBON BY THE WET OXIDATION METHOD [J].
AIKEN, GR .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1992, 26 (12) :2435-2439
[3]   Catalytic decomposition of organic anions in alkaline radioactive waste: IV. Oxidation of glycolate with persulfate in the presence of Ru(III) [J].
Anan'ev A.V. ;
Shilov V.P. .
Radiochemistry, 2006, 48 (2) :133-135
[4]   Radical generation by the interaction of transition metals with common oxidants [J].
Anipsitakis, GP ;
Dionysiou, DD .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (13) :3705-3712
[5]  
[Anonymous], 2004, P 4 INT C REM CHLOR
[6]   The Elbs and Boyland-Sims peroxydisulfate oxidations [J].
Behrman, E. J. .
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2
[7]  
BERLIN AA, 1986, KINET CATAL+, V27, P34
[8]  
Bjerg, 2006, P 5 INT C REM CHLOR
[9]  
Block P.A., 2004, P 4 INT C REM CHLOR
[10]  
BLOCK PA, P 3 INT C OX RED TEC
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