Synthesis and crystal structure of unprecedented phosphine adducts of d1-aryl imido-vanadium(IV) complexes

被引：37

作者：

Lorber, C ^{[1
]}

Choukroun, R ^{[1
]}

Donnadieu, B ^{[1
]}

机构：

[1] CNRS, UPR 8241, Chim Coordinat Lab, F-31077 Toulouse 04, France

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 03期

关键词：

D O I：

10.1021/ic026089m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the imido precursor [V(NAr)Cl-2](n) (1) (Ar = 2,6-i-Pr2C6H3) with 3 equiv of PMe2Ph yields the monomeric complex [V(=NAr)Cl-2(PMe2Ph)(2)] (2). Reacting 1 with 1.5 equiv of dmpe or 1 equiv of dppm affords the dimeric complexes [V(=NAr)Cl-2-(dmpe)](2)(mu-P,P'-dmpe) (3) and [V(=NAr)Cl-2(dPPM)](2) (4), respectively. Complexes 2-4 have been fully characterized by spectroscopic methods, magnetism studies, and X-ray crystallography.

引用

页码：673 / 675

页数：3

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