Spectroscopic properties of anion radicals studied using pulse radiolysis

被引：10

作者：

Samant, Vaishali ^{[1
]}

Singh, Ajay K. ^{[1
]}

Mukherjee, Tulsi ^{[1
]}

Palit, Dipak K. ^{[1
]}

机构：

[1] Bhabha Atom Res Ctr, Radiat & Photochem Div, Bombay 400085, Maharashtra, India

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2006年 / 32卷 / 08期

关键词：

anion radical; pulse radiolysis; electron transfer;

D O I：

10.1163/156856706778606499

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The anion radicals of benzophenone, amino derivatives of benzophenone, flourenone, furil and antharcene have been generated by pulse radiolysis in acetonitrile solution and their spectroscopic and kinetic properties have been characterized. The G-value for generation of anion radicals in acetonitrile has been measured to be 1.01 +/- 0.1 per 100 eV. We have also investigated the electrontransfer reactions from anion radicals of one kind of solutes to the ground state of another solute. This study has demonstrated that pulse radiolysis can be a useful technique for generation and characterization of anion radicals and for studying electron-transfer reactions using acetonitrile as solvent.

引用

页码：767 / 776

页数：10

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