4,4,6-trimethyl-1,3,2-dioxaborinane: A practical reagent for palladium-catalyzed borylation of aryl halides

被引：18

作者：

Murata, Miki ^{[1
]}

Oda, Takeshi ^{[1
]}

Watanabe, Shinji ^{[1
]}

Masuda, Yuzuru ^{[1
]}

机构：

[1] Kitami Inst Technol, Dept Mat Sci, Kitami, Hokkaido 0908507, Japan

来源：

SYNTHESIS-STUTTGART | 2007年 / 03期

关键词：

boron; palladium; catalysis; cross-coupling; aryl halides;

D O I：

10.1055/s-2006-958962

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium-catalyzed borylation of aryl iodides with 4,4,6-trimethyl-1,3,2-dioxaborinane is described. The mild reaction conditions employed allow for aryl iodides with a wide variety of functional groups to be tolerated. The products of this borylation were coupled with aryl halides to give biaryls in good yields.

引用

页码：351 / 354

页数：4

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