4,4,6-trimethyl-1,3,2-dioxaborinane: A practical reagent for palladium-catalyzed borylation of aryl halides

被引：18
|
作者：
Murata, Miki [1 ]
Oda, Takeshi [1 ]
Watanabe, Shinji [1 ]
Masuda, Yuzuru [1 ]
机构：
[1] Kitami Inst Technol, Dept Mat Sci, Kitami, Hokkaido 0908507, Japan
来源：
SYNTHESIS-STUTTGART | 2007年 / 03期
关键词：
boron; palladium; catalysis; cross-coupling; aryl halides;
D O I：
10.1055/s-2006-958962
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The palladium-catalyzed borylation of aryl iodides with 4,4,6-trimethyl-1,3,2-dioxaborinane is described. The mild reaction conditions employed allow for aryl iodides with a wide variety of functional groups to be tolerated. The products of this borylation were coupled with aryl halides to give biaryls in good yields.
引用
收藏
页码：351 / 354
页数：4
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