Molecular clips and tweezers with corannulene pincers

被引：45

作者：

Kobryn, Lesya ^{[1
]}

Henry, William P. ^{[1
]}

Fronczek, Frank R. ^{[2
]}

Sygula, Renata ^{[1
]}

Sygula, Andrzej ^{[1
]}

机构：

[1] Mississippi State Univ, Dept Chem, Mississippi State, MS 39762 USA

[2] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 51期

关键词：

D O I：

10.1016/j.tetlet.2009.09.177

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Application of the synthetic methodology developed in our laboratory yields molecular clips and tweezers with corannulene pincers and cyclooctadiene or cyclooctatetraene tethers. These highly nonplanar systems possess a potential for binding guest molecules of various sizes. One of the clips, bis(benzocorannulene)[a,e]cyclooctadiene, exists in a 'open' chair conformation encapsulating solvating nitrobenzene in the solid state, while it is expected to prefer an internally pi-pi stacked twist-boat conformation in the gas phase. (c) 2009 Elsevier Ltd. All rights reserved.

引用

页码：7124 / 7127

页数：4

共 18 条

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