Highly asymmetric cobalt-catalyzed aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN3)

被引：114
|
作者：
Subbarayan, Velusamy [1 ]
Ruppel, Joshua V. [1 ]
Zhu, Shifa [1 ]
Perman, Jason A. [1 ]
Zhang, X. Peter [1 ]
机构：
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 28期
关键词：
C-H AMINATION; SILYL ENOL ETHERS; ENANTIOSELECTIVE AZIRIDINATION; OLEFIN AZIRIDINATION; ARYL AZIDES; DIPHENYLPHOSPHORYL AZIDE; ARYLSULFONYL AZIDES; NITRENE PRECURSORS; COPPER-COMPLEXES; NITROGEN-SOURCES;
D O I：
10.1039/b905727g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Co(II)-based catalytic system has been developed for asymmetric aziridination of alkenes with trichloroethoxysulfonyl azide (TcesN(3)) under mild conditions, forming the corresponding N-Tces-aziridines in high yields and excellent enantioselectivities.
引用
收藏
页码：4266 / 4268
页数：3
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