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FORMAL TOTAL SYNTHESIS OF (±)-STRICTAMINE
被引:6
|作者:
Sato, Keigo
[1
]
Takanashi, Noriyuki
[1
]
Kogure, Noriyuki
[1
]
Kitajima, Mariko
[1
]
Takayama, Hiromitsu
[1
]
机构:
[1] Chiba Univ, Grad Sch Pharmaceut Sci, Lab Biofunct Mol Chem, Chuo Ku, 1-8-1 Inohana, Chiba 2608675, Japan
基金:
日本学术振兴会;
关键词:
ASYMMETRIC TOTAL-SYNTHESIS;
AKUAMMILINE ALKALOIDS;
INDOLE ALKALOIDS;
STRICTAMINE;
ECHITAMINE;
CONSTRUCTION;
REARRANGEMENT;
SCHOLARISINE;
CYCLIZATION;
FRAMEWORK;
D O I:
10.3987/COM-18-S(T)24
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
A formal total synthesis of an alcuammiline-type indole alkaloid, (+/-)-strictamine, which features ozonolysis, the Staudinger reaction, and the aza-Wittig reaction to construct its D-ring, is reported.
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页码:365 / 382
页数:18
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