Synthesis, structure and properties of a novel metal tellurobromide -: Hg2TeBr3

被引:8
作者
Chen, Wen-Tong [1 ]
Li, Xin-Fa [1 ]
Luo, Qiu-Yan [1 ]
Xu, Ya-Ping [1 ]
Zhou, Guang-Pei [1 ]
机构
[1] JingGangShan Univ, Coll Chem & Chem Engn, Jiangxi Province Key Lab Coordinat Chem, Jian 343009, Jiangxi, Peoples R China
关键词
chalcogenide; halide; mercury; SEM/EDS; tellurium; CRYSTAL-STRUCTURE; OPTICAL-PROPERTIES; PHASE-EQUILIBRIA; RB; CS; CHALCOGENIDES; CHEMISTRY; TELLURIDE; SULFIDE; SELENOPHOSPHATES;
D O I
10.1016/j.inoche.2006.12.019
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel metal tellurobromide Hg2TeBr3 (1) was obtained by solid-state reactions and structurally characterized. Compound 1 is characterized by a 2D layer structure. Optical absorption spectra of 1 reveal the presence of sharp optical gap of 2.03 eV. TG-DTA measurement shows that compound 1 is thermally stable up to 173 degrees C. The composition of 1 is well confirmed by the semiquantitative microscope analysis. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:427 / 431
页数:5
相关论文
共 67 条
  • [51] STRAND D, 1983, P SOC PHOTO-OPT INST, V420, P200, DOI 10.1117/12.936069
  • [52] Stabilization of uranyl cations in molten sodium polysulfide and formation of the novel solid oxysulfide Na-4(UO2)Cu2S4
    Sutorik, AC
    Kanatzidis, MG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (33) : 7901 - 7902
  • [53] Structural evidence for ferroelectricity in Eu2GeS4
    Tampier, M
    Johrendt, D
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2001, 158 (02) : 343 - 348
  • [54] Preparation and reactions of sodium telluride, Na2Te - Crystal structure of [Na(CH3OH)(3)]2Te2
    Thiele, KH
    Steinicke, A
    Dumichen, U
    Neumuller, B
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (02): : 231 - 234
  • [55] Tillinski R, 1998, Z ANORG ALLG CHEM, V624, P1285, DOI 10.1002/(SICI)1521-3749(199808)624:8<1285::AID-ZAAC1285>3.0.CO
  • [56] 2-5
  • [57] Voroshilov YV, 1996, ZH NEORG KHIM+, V41, P287
  • [58] VOROSHILOV YV, 1996, INORG MAT USSR, V32, P1466
  • [59] Wang C, 2002, ANGEW CHEM INT EDIT, V41, P1959, DOI 10.1002/1521-3773(20020603)41:11<1959::AID-ANIE1959>3.0.CO
  • [60] 2-I