Effect of the Polymeric Stabilizer in the Aqueous Phase Fischer-Tropsch Synthesis Catalyzed by Colloidal Cobalt Nanocatalysts

被引：3

作者：

Delgado, Jorge A. ^{[1
]}

Claver, Carmen ^{[1
,2
]}

Castillon, Sergio ^{[3
]}

Curulla-Ferre, Daniel ^{[4
]}

Godard, Cyril ^{[2
]}

机构：

[1] Chem Ctr Technol, Tarragona 43007, Spain

[2] Univ Rovira & Virgili, Physicochem & Inorgan Chem Dept, E-43007 Tarragona, Spain

[3] Univ Rovira & Virgili, Analyt & Organ Chem Dept, E-43007 Tarragona, Spain

[4] Total Res & Technol Feluy, B-7181 Seneffe, Belgium

来源：

NANOMATERIALS | 2017年 / 7卷 / 03期

关键词：

aqueous phase Fischer-Tropsch synthesis; cobalt nanoparticles; polymeric stabilizers; BOROHYDRIDE REDUCTION; SILVER NANOPARTICLES; SUPPORTED COBALT; BORON PROMOTION; IONIC LIQUIDS; SHAPE CONTROL; SELECTIVITY; SIZE; NANOCRYSTALS; OXIDATION;

D O I：

10.3390/nano7030058

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of small and well defined cobalt nanoparticles were synthesized by the chemical reduction of cobalt salts in water using NaBH4 as a reducing agent and using various polymeric stabilizers. The obtained nanocatalysts of similar mean diameters (ca. 2.6 nm) were fully characterized and tested in the aqueous phase Fischer-Tropsch Synthesis (AFTS). Interestingly, the nature and structure of the stabilizers used during the synthesis of the CoNPs affected the reduction degree of cobalt and the B-doping of these NPs and consequently, influenced the performance of these nanocatalysts in AFTS.

引用

页数：11