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Multi-functional carbon dots for visual detection of picric acid and white-light emission
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作者:

Vidya, T.
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Natl Inst Technol Calicut NITC, Photon Mat & Devices Lab, Dept Phys, Kozhikode 673601, Kerala, India Natl Inst Technol Calicut NITC, Photon Mat & Devices Lab, Dept Phys, Kozhikode 673601, Kerala, India

Anupama, M.
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Natl Inst Technol Calicut NITC, Photon Mat & Devices Lab, Dept Phys, Kozhikode 673601, Kerala, India Natl Inst Technol Calicut NITC, Photon Mat & Devices Lab, Dept Phys, Kozhikode 673601, Kerala, India

Muhammed, Sajan
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Natl Inst Technol Calicut NITC, Photon Mat & Devices Lab, Dept Phys, Kozhikode 673601, Kerala, India Natl Inst Technol Calicut NITC, Photon Mat & Devices Lab, Dept Phys, Kozhikode 673601, Kerala, India

Joseph, Julin
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Natl Inst Technol Calicut NITC, Photon Mat & Devices Lab, Dept Phys, Kozhikode 673601, Kerala, India Natl Inst Technol Calicut NITC, Photon Mat & Devices Lab, Dept Phys, Kozhikode 673601, Kerala, India

Anappara, Aji A.
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Natl Inst Technol Calicut NITC, Photon Mat & Devices Lab, Dept Phys, Kozhikode 673601, Kerala, India Natl Inst Technol Calicut NITC, Photon Mat & Devices Lab, Dept Phys, Kozhikode 673601, Kerala, India
机构:
[1] Natl Inst Technol Calicut NITC, Photon Mat & Devices Lab, Dept Phys, Kozhikode 673601, Kerala, India
关键词:
Picric acid sensing;
Visual detection;
White-light emission;
Fluorescence;
Carbon dots;
QUANTUM DOTS;
SELECTIVE DETECTION;
AQUEOUS-SOLUTION;
SENSITIVE DETECTION;
FACILE SYNTHESIS;
PHOTOLUMINESCENCE;
EXCITATION;
WASTE;
D O I:
10.1016/j.materresbull.2021.111223
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
Herein we report the synthesis of multifunctional carbon dots (CDs) through microwave-assisted pyrolysis of 2-aminoterephthalic acid and polyethylene glycol. The CDs exhibited relatively high photoluminescence quantum yield of about 67 %, and has been found to be selective and ultrasensitive to the nitroaromatic explosive picric acid, with a detection limit as low as 18 nM. The visual detection of the analyte was realized using CDs in the solid-phase, after coating the dots on silica-based thin-layer chromatographic plates. Furthermore, the broad-band luminescence was exploited for UV-to-visible light conversion, to obtain the color parameters of CIE (0.35, 0.33), CRI of 92 and CCT of 5246 K, representing the cool, white-gamut region of 1931 CIE chromaticity diagram.
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