Transition times in the low-noise limit of stochastic dynamics

被引:24
作者
Malinin, Sergey V. [1 ]
Chernyak, Vladimir Y. [1 ]
机构
[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA
基金
美国国家科学基金会;
关键词
noise; phase transformations; stochastic processes; LARGE FLUCTUATIONS; OPTIMAL PATHS; WKB TREATMENT; EXIT PROBLEM; SYSTEMS; STATES; SPECTROSCOPY; DIFFUSION; WATER; DISTRIBUTIONS;
D O I
10.1063/1.3278440
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We study the transition time distribution for a particle moving between two wells of a multidimensional potential in the low-noise limit of overdamped Langevin dynamics. Possible transition paths are restricted to a thin tube surrounding the most probable trajectory. We demonstrate that finding the transition time distribution reduces to a one-dimensional problem. The resulting transition time distribution has a universal and compact form. We suggest that transition barriers can be estimated from a single-temperature experiment if both the life times and the transition times are measured.
引用
收藏
页数:11
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