Frequency and Temperature Dependence of Dielectric Behaviors for Conductive Acrylic Composites

被引：21

作者：

Cetiner, Suat ^{[1
]}

Sirin, Seyma ^{[1
]}

Olariu, Marius ^{[2
]}

Sarac, A. Sezai ^{[3
]}

机构：

[1] Kahramanmaras Sutcu Imam Univ, Dept Text Engn, TR-46050 Kahramanmaras, Turkey

[2] Tech Univ Gh Asachi Iasi, Dept Elect Measurements & Mat, Bdul D Mangeron 53-55, Iasi, Romania

[3] Istanbul Tech Univ, Dept Chem Polymer Sci & Technol, TR-80626 Istanbul, Turkey

来源：

ADVANCES IN POLYMER TECHNOLOGY | 2016年 / 35卷 / 01期

关键词：

Conducting materials; Doping; Nanoparticles; Polymerization; Thin films; POLYPYRROLE; POLYMERIZATION; FABRICATION; FILMS;

D O I：

10.1002/adv.21523

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

In this study, acrylic-based conductive polymeric composite thin films were prepared by in situ chemical polymerization of pyrrole (Py) in the case of ammonium persulfate (APS) and iron(III) chloride (FeCl3). Composite thin films were produced by the solution casting method. The effect of polypyrrole (PPy) content and the type of oxidant on the morphological and dielectric properties were investigated. Temperature- and frequency-dependent dielectric properties were also studied in a frequency domain starting from 0.01 Hz to 10 MHz and in a temperature domain from 35 to 195 degrees C. The results revealed that the dielectric constant and dielectric loss increased, whereas temperature and the highest dielectric values were obtained in the case of APS. The density of interconnected pores enwrapped with PPy under the surface improved the electrical/dielectric properties of the composite thin films.

引用

页数：10

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