Grain-boundary and crack effects on the dielectric response of high-permittivity films and ceramics

被引:54
作者
Rychetsky, I [1 ]
Petzelt, J [1 ]
Ostapchuk, T [1 ]
机构
[1] Acad Sci Czech Republ, Inst Phys, Prague 18221 8, Czech Republic
关键词
D O I
10.1063/1.1525394
中图分类号
O59 [应用物理学];
学科分类号
摘要
Grain-boundary and crack effects on the dielectric response of high-permittivity films and ceramics were analyzed using the generalized effective-medium approximation. It was demonstrated that the brick-wall and coated spheres models, which become equivalent for a small porosity, best describe the strong reduction of the dielectric response and hardening of the soft-mode frequency recently revealed in SrTiO3 films and PbZrO3 ceramics. (C) 2002 American Institute of Physics.
引用
收藏
页码:4224 / 4226
页数:3
相关论文
共 24 条
[1]  
[Anonymous], ADV SOLID STATE PHYS
[2]  
ASHCROFT NW, 1976, SOLID STATE PHYS, P547
[3]  
BERGMAN DJ, 1992, SOLID STATE PHYS, V46, P148
[5]  
Carr G. L., 1985, Infrared and Millimeter Waves, V13, P171
[6]   Far-infrared spectroscopy of a SrTiO3 thin film [J].
Fedorov, I ;
Zelezny, V ;
Petzelt, J ;
Trepakov, V ;
Jelinek, M ;
Trtik, V ;
Cernansky, M ;
Studnicka, V .
FERROELECTRICS, 1998, 208 (1-4) :413-427
[7]   The role of interfaces on an apparent grain size effect on the dielectric properties for ferroelectric barium titanate ceramics [J].
Frey, MH ;
Xu, Z ;
Han, P ;
Payne, DA .
FERROELECTRICS, 1998, 206 (1-4) :337-353
[8]  
Gervais F, 1983, INFRARED MILLIMETER, V8, P279
[9]   A VARIATIONAL APPROACH TO THEORY OF EFFECTIVE MAGNETIC PERMEABILITY OF MULTIPHASE MATERIALS [J].
HASHIN, Z ;
SHTRIKMAN, S .
JOURNAL OF APPLIED PHYSICS, 1962, 33 (10) :3125-&
[10]   Dielectric response of microcomposite ferroelectrics [J].
Hudak, O ;
Rychetsky, I ;
Petzelt, J .
FERROELECTRICS, 1998, 208 (1-4) :429-447