Viscosity effect on epoxy-diamine/metal interphases - Part II: Mechanical resistance and durability

被引:22
作者
Montois, Patrick [1 ]
Nassiet, Valerie [1 ]
Petit, Jacques Alain [1 ]
Adrian, Denise [1 ]
机构
[1] Ecole Natl Ingn Tarbes, Lab Genie Prod, Equipe Interfaces & Mat Fonct, F-65016 Tarbes, France
关键词
epoxy; titanium and alloys; interphase; rupture; ageing;
D O I
10.1016/j.ijadhadh.2006.03.001
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Under certain conditions of polymerization, a thick interphase can appear in the epoxy/titanium alloys adhesive bonded joints. The hardener nature change, which created the interphase, changes considerably the mechanical properties and ageing resistance of the assemblies. By measurement of fracture energies and physicochemical analysis of the failure facies, this work shows the interphase effect on the adhesive bonded joints mechanical behaviour. Also the beneficial of the interphase formation on ageing resistance is shown. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:145 / 155
页数:11
相关论文
共 23 条
[1]  
AUFRAY M, 2003, P JADH 2003, V68
[2]   THE GLASS-TRANSITION TEMPERATURES OF HIGHLY CROSSLINKED NETWORKS - CURED EPOXY-RESINS [J].
BANKS, L ;
ELLIS, B .
POLYMER, 1982, 23 (10) :1466-1472
[3]   Organo-metallic complex characterization formed when liquid epoxy-diamine mixtures are applied onto metallic substrates [J].
Bentadjine, S ;
Petiaud, R ;
Roche, AA ;
Massardier, V .
POLYMER, 2001, 42 (14) :6271-6282
[4]   The formation of epoxy/metal interphases: Mechanisms and their role in practical adhesion [J].
Bouchet, J ;
Roche, AA .
JOURNAL OF ADHESION, 2002, 78 (09) :799-830
[5]   The durability of adhesive joints in the presence of water [J].
Bowditch, MR .
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 1996, 16 (02) :73-79
[6]  
BROCKMANN W, 1988, COUCHES MINCES
[7]  
Brockmann W., 1986, Int.J. Adhes. Adhes, V6, P115, DOI [10.1016/0143-7496(86)90016-3, DOI 10.1016/0143-7496(86)90016-3]
[8]  
CHATEAUMINOIS A, 1991, THESIS U CLAUDE BERN
[9]   THE MECHANICS OF THE WEDGE TEST [J].
COGNARD, J .
JOURNAL OF ADHESION, 1986, 20 (01) :1-13
[10]  
COGNARD J, 1990, VIDE COUCHES MINCE S, V251, P93