Alkylation of benzene with short-chain olefins over MCM-22 zeolite:: Catalytic behaviour and kinetic mechanism

被引：273

作者：

Corma, A ^{[1
]}

Martínez-Soria, V

Schnoeveld, E

机构：

[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

[2] Univ Valencia, Dept Engn Quim, E-46100 Burjassot, Spain

来源：

JOURNAL OF CATALYSIS | 2000年 / 192卷 / 01期

基金：

欧盟地平线“2020”;

关键词：

benzene alkylation with MCM-22 zeolite; benzene alkylation on Beta zeolite; cumene and ethylbenzene production on; zeolites;

D O I：

10.1006/jcat.2000.2849

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Benzene alkylation with ethene and propene has been carried out under liquid-phase reaction conditions over zeolites MCM-22, Beta, and ZSM-5. MCM-22 seems to be a good catalyst for benzene alkylation especially with propene, showing high activity and stability and good selectivity. Kinetic experiments show that alkylation with propene follows an Eley-Rideal type mechanism. (C) 2000 Academic Press.

引用

页码：163 / 173

页数：11

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