Glycerol-based solvents as green reaction media in epoxidations with hydrogen peroxide catalysed by bis[3,5-bis(trifluoromethyl)-diphenyl] diselenide

被引：46

作者：

Garcia-Marin, Hector ^{[1
]}

van der Toorn, John C. ^{[2
]}

Mayoral, Jose A. ^{[3
]}

Garcia, Jose I. ^{[1
]}

Arends, Isabel W. C. E. ^{[2
]}

机构：

[1] Univ Zaragoza, CSIC, Fac Ciencias, Inst Ciencia Mat Aragon,Dept Organ Chem, E-50009 Zaragoza, Spain

[2] Delft Univ Technol, Lab Biocatalysis & Organ Chem, NL-2628 BL Delft, Netherlands

[3] Univ Zaragoza, Fac Ciencias, Inst Univ Catalisis Homogenea, E-50009 Zaragoza, Spain

来源：

GREEN CHEMISTRY | 2009年 / 11卷 / 10期

关键词：

SOLVATOCHROMIC COMPARISON METHOD; SOLVATION ENERGY RELATIONSHIPS; FLUORINATED ALCOHOLS; OLEFIN EPOXIDATION; ENVIRONMENTAL ASSESSMENT; PI-STAR; ACTIVATION; OXIDATION; SELENOXIDE; CONVERSION;

D O I：

10.1039/b913052g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A family of glycerol-based solvents, consisting of eighteen 1,3-dialkoxy-2-propanols and 1,2,3-trialkoxypropanes, both symmetrically and unsymmetrically substituted at terminal positions, has been tested as new solvents in cyclooctene epoxidation with hydrogen peroxide, using a diselenide catalyst, but also without a catalyst. A quantitative relationship between the reactivity and solvent polarity properties has been developed through statistical linear regression analyses, and the predictive ability of the resulting equation has been demonstrated.

引用

页码：1605 / 1609

页数：5

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