A Comparative Study of Electrochemical, Spectroscopic and Structural Properties of Phenyl, Thienyl and Furyl Substituted Ethylenes

被引：6
作者：
Viglianti, Lucia [2 ,4 ]
Villafiorita-Monteleone, Francesca [3 ]
Botta, Chiara [3 ]
Mussini, Patrizia R. [2 ]
Ortoleva, Emanuele [2 ]
Cauteruccio, Silvia [2 ]
Licandro, Emanuela [2 ]
Baldoli, Clara [1 ]
机构：
[1] Ist Sci & Tecnol Molecolari, CNR, Via C Golgi 19, I-20133 Milan, Italy
[2] Univ Milan, Dipartimento Chim, Via C Golgi 19, I-20133 Milan, Italy
[3] Ist Studio Macromol, CNR, Via A Corti 12, I-20133 Milan, Italy
[4] Hong Kong Univ Sci & Technol, Dept Chem, Clear Water Bay, Kowloon, Hong Kong, Peoples R China
来源：
CHEMISTRYSELECT | 2017年 / 2卷 / 09期
关键词：
alkenes; electrochemistry; electrooligomerization; heterocycles; solid state emission; AGGREGATION-INDUCED EMISSION; MOLECULAR-ORBITAL METHODS; OXIDATIVE POLYMERIZATION; DOPED POLYMERS; TETRAPHENYLETHENE; ELECTROLUMINESCENCE; MECHANOCHROMISM;
D O I：
10.1002/slct.201700109
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
a detailed electrochemical and photophysical comparative study of three parallel series of phenyl, thienyl and furyl substituted ethylenes has been carried out, implemented by the computational calculation of selected terms. Relationships have been highlighted between molecular structure (number and type of aromatic rings) and important functional properties (in particular, electronic features and oligomerization ability). Interestingly, some of the studied heteroaryl-ethylenes show emission in the solid state displaying an aggregation-induced emission behavior.
引用
收藏
页码：2763 / 2773
页数：11
相关论文
共 50 条
  • [41] Synthesis, spectroscopic, magnetic and electrochemical properties of Cu(II) and Fe(III) complexes with the new ligand N,N'-[1,1'-dithiobis(phenyl)]bis(5'-methoxysalicylaldimine)
    Gili, P
    Reyes, MGM
    Zarza, PM
    Machado, ILF
    daSilva, MFCG
    Lemos, MANDA
    Pombeiro, AJL
    INORGANICA CHIMICA ACTA, 1996, 244 (01) : 25 - 36
  • [42] The selective monobromination of a highly sterically encumbered corrole: Structural and spectroscopic properties of Fe(Cl)(2-bromo-5,10,15-tris(triphenyl)phenyl corrole)
    Alvarado, Jessica G.
    Cummins, Daniel C.
    Diaconescu, Andrada C.
    Siegler, Maxime A.
    Goldberg, David P.
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2021, 25 (10N12) : 1176 - 1185
  • [43] A density functional study of oxorhenium(V) complexes incorporating quinoline or isoquinoline carboxylic acids: structural, spectroscopic, and electronic properties
    Machura, B.
    Wolff, M.
    STRUCTURAL CHEMISTRY, 2014, 25 (06) : 1607 - 1623
  • [44] Study on the effects of deep eutectic solvents as a reaction media on the micromorphology of hydrogen-substituted graphyne and its adsorption and electrochemical properties
    Li, Yaofen
    Wang, Lijuan
    Yan, Hongyuan
    Liu, Haiyan
    Zhu, Tao
    Tang, Baokun
    JOURNAL OF MOLECULAR LIQUIDS, 2022, 349
  • [45] New Nanocomposites Based on Poly (o-phenylenediamine) and ZrO2 Nanoparticles: A Study of Spectroscopic, Thermal, Optical and Electrochemical Properties
    Hamam, Nabil
    Boumeftah, Ali
    Bahoussi, Sakina
    Belmokhtar, Abdelkader
    Benyoucef, Abdelghani
    Bekhti, Mohamed Amine
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2024, 34 (11) : 5587 - 5595
  • [46] Structures and spectroscopic properties of nonperipherally and peripherally substituted metal-free phthalocyanines: A substitution effect study based on density functional theory calculations
    Zhong, Aimin
    Zhang, Yuexing
    Bian, Yongzhong
    JOURNAL OF MOLECULAR GRAPHICS & MODELLING, 2010, 29 (03) : 470 - 480
  • [47] Electrochemical study on cytochrome c peroxidase from Paracoccus denitrificans: a shifting pattern of structural and thermodynamic properties as the enzyme is activated
    Helder Lopes
    Graham W. Pettigrew
    Isabel Moura
    José J. G. Moura
    JBIC Journal of Biological Inorganic Chemistry, 1998, 3 : 632 - 642
  • [48] Electrochemical study on cytochrome c peroxidase from Paracoccus denitrificans:: a shifting pattern of structural and thermodynamic properties as the enzyme is activated
    Lopes, H
    Pettigrew, GW
    Moura, I
    Moura, JJG
    JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 1998, 3 (06): : 632 - 642
  • [49] Nitrogen-Rich Bis-1,2,4-triazoles-A Comparative Study of Structural and Energetic Properties
    Dippold, Alexander A.
    Klapoetke, Thomas M.
    CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (52) : 16742 - 16753
  • [50] Reactions of azulenes with 1,2-diaryl-1,2-ethanediols in methanol in the presence of hydrochloric acid: comparative studies on products, crystal structures, and spectroscopic and electrochemical properties
    Nakatsuji, M
    Hata, Y
    Fujihara, T
    Yamamoto, K
    Sasaki, M
    Takekuma, H
    Yoshihara, M
    Minematsu, T
    Takekuma, S
    TETRAHEDRON, 2004, 60 (28) : 5983 - 6000
12345