A Comparative Study of Electrochemical, Spectroscopic and Structural Properties of Phenyl, Thienyl and Furyl Substituted Ethylenes

被引：6
作者：
Viglianti, Lucia [2 ,4 ]
Villafiorita-Monteleone, Francesca [3 ]
Botta, Chiara [3 ]
Mussini, Patrizia R. [2 ]
Ortoleva, Emanuele [2 ]
Cauteruccio, Silvia [2 ]
Licandro, Emanuela [2 ]
Baldoli, Clara [1 ]
机构：
[1] Ist Sci & Tecnol Molecolari, CNR, Via C Golgi 19, I-20133 Milan, Italy
[2] Univ Milan, Dipartimento Chim, Via C Golgi 19, I-20133 Milan, Italy
[3] Ist Studio Macromol, CNR, Via A Corti 12, I-20133 Milan, Italy
[4] Hong Kong Univ Sci & Technol, Dept Chem, Clear Water Bay, Kowloon, Hong Kong, Peoples R China
来源：
CHEMISTRYSELECT | 2017年 / 2卷 / 09期
关键词：
alkenes; electrochemistry; electrooligomerization; heterocycles; solid state emission; AGGREGATION-INDUCED EMISSION; MOLECULAR-ORBITAL METHODS; OXIDATIVE POLYMERIZATION; DOPED POLYMERS; TETRAPHENYLETHENE; ELECTROLUMINESCENCE; MECHANOCHROMISM;
D O I：
10.1002/slct.201700109
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
a detailed electrochemical and photophysical comparative study of three parallel series of phenyl, thienyl and furyl substituted ethylenes has been carried out, implemented by the computational calculation of selected terms. Relationships have been highlighted between molecular structure (number and type of aromatic rings) and important functional properties (in particular, electronic features and oligomerization ability). Interestingly, some of the studied heteroaryl-ethylenes show emission in the solid state displaying an aggregation-induced emission behavior.
引用
收藏
页码：2763 / 2773
页数：11
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