Dibutyltin dimethoxide and BINAP•silver(I) complex-catalyzed asymmetric aldol reaction of alkenyl trichloro acetates with aldehydes

被引：10

作者：

Yanagisawa, Akira ^{[1
]}

Ichikawa, Toshikazu

Arai, Takayoshi

机构：

[1] Chiba Univ, Fac Sci, Dept Chem, Inage Ku, Chiba 2638522, Japan

[2] Chiba Univ, Grad Sch Sci & Technol, Inage Ku, Chiba 2638522, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 1-3期

关键词：

asymmetric catalysis; aldol reaction; tin alkoxide-1; BINAP; silver; alkenyl esters; aldehydes;

D O I：

10.1016/j.jorganchem.2006.08.048

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A catalytic asymmetric aldol reaction of alkenyl trichloroacetates with aldehydes was achieved using dibutyltin dimethoxide and BINAP (.) silver(I) complex as catalysts in a mixed solvent consisting of THF and MeOH. Various optically active beta-hydroxy ketones were diastereoselectively obtained not only from aromatic and alpha,beta-unsaturated aldehydes but also from an aliphatic aldehyde with good enantioselectivity up to 92% ee. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：550 / 553

页数：4

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