Activation of carbon dioxide and synthesis of propylene carbonate

被引：0

作者：

Zhang, YJ ^{[1
]}

Feng, YE ^{[1
]}

Pan, YZ ^{[1
]}

He, R ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2002年 / 13卷 / 11期

关键词：

cycloaddition reaction; carbon dioxide; propylene oxide; propylene carbonate; tetra-tert-butyl metal phthalocyanine;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cycloaddition of carbon dioxide and propylene oxide to propylene carbonate catalyzed by tetra-tert-butyl metal phthalocyanine in the presence of tributylamine (TBA) shows higher yield than catalyzed by unsubstituted metal phthalocyanine. Comparing different catalysts of diverse metals, (t-Bu)(4)PcMg is more active than (t-Bu)(4)PcFe. But (t-Bu)(4)PcCo and (t-Bu)(4)PcNi only have low catalytic activities towards the reaction. Moreover, the yield will increase as the temperature increases.

引用

页码：1047 / 1050

页数：4

共 50 条

[21] Stereocomplex of Poly(propylene carbonate): Synthesis of Stereogradient Poly(propylene carbonate) by Regio- and Enantioselective Copolymerization of Propylene Oxide with Carbon Dioxide
Nakano, Koji
Hashimoto, Shinichi
Nakamura, Mitsuru
Kamada, Toshihiro
Nozaki, Kyoko
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (21) : 4868 - 4871
[22] Chemical fixation of carbon dioxide to propylene carbonate in ionic liquids
Kim, YJ
Cheong, M
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2002, 23 (07) : 1027 - 1028
[23] Direct synthesis of propylene carbonate from propylene and carbon dioxide catalyzed by quaternary ammonium heteropolyphosphatotungstate-TBAB system
Zhao, Gongda
Zhang, Yi
Zhang, Hengyun
Li, Jun
Gao, Shuang
JOURNAL OF ENERGY CHEMISTRY, 2015, 24 (03) : 353 - 358
[24] Synthesis of propylene carbonate from carbon dioxide using trans-dichlorotetrapyridineruthenium(II) as catalyst
Bu, Zhanwei
Wang, Zhiqiang
Yang, Lirong
Cao, Shaokui
APPLIED ORGANOMETALLIC CHEMISTRY, 2010, 24 (11) : 813 - 816
[25] Synthesis of dimethyl carbonate from propylene oxide, carbon dioxide and methanol on KOH/4A molecular sieve catalyst
Li, Y
Zhao, XQ
Wang, YJ
CHINESE JOURNAL OF CATALYSIS, 2004, 25 (08) : 633 - 636
[26] Synthesis of Propylene Carbonate from Carbon Dioxide and Propylene Oxide Using Zn-Mg-Al Composite Oxide as High-efficiency Catalyst
Wei-Li Dai
Shuang-Feng Yin
Rui Guo
Sheng-Lian Luo
Xin Du
Chak-Tong Au
Catalysis Letters, 2010, 136 : 35 - 44
[27] Synthesis of Propylene Carbonate from Carbon Dioxide and Propylene Oxide Using Zn-Mg-Al Composite Oxide as High-efficiency Catalyst
Dai, Wei-Li
Yin, Shuang-Feng
Guo, Rui
Luo, Sheng-Lian
Du, Xin
Au, Chak-Tong
CATALYSIS LETTERS, 2010, 136 (1-2) : 35 - 44
[28] Poly(Propylene Carbonate) from Carbon Dioxide: Challenges for Large-Scale Application
Korashvili, Revaz
Noernberg, Benjamin
Bornholdt, Nick
Borchardt, Endres
Luinstra, Gerrit A.
CHEMIE INGENIEUR TECHNIK, 2013, 85 (04) : 437 - 446
[29] Carbon dioxide utilization in propylene carbonate production process
Esmaeili-Chelan, Erfan
Bahadori, Fatemeh
SCIENTIFIC REPORTS, 2024, 14 (01):
[30] A ruthenium complex exhibiting high catalytic efficiency for the formation of propylene carbonate from carbon dioxide
Bu, Zhanwei
Qin, Gang
Cao, Shaokui
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 277 (1-2) : 35 - 39

← 1 2 3 4 5 →