Activation of carbon dioxide and synthesis of propylene carbonate

被引：0

作者：

Zhang, YJ ^{[1
]}

Feng, YE ^{[1
]}

Pan, YZ ^{[1
]}

He, R ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2002年 / 13卷 / 11期

关键词：

cycloaddition reaction; carbon dioxide; propylene oxide; propylene carbonate; tetra-tert-butyl metal phthalocyanine;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cycloaddition of carbon dioxide and propylene oxide to propylene carbonate catalyzed by tetra-tert-butyl metal phthalocyanine in the presence of tributylamine (TBA) shows higher yield than catalyzed by unsubstituted metal phthalocyanine. Comparing different catalysts of diverse metals, (t-Bu)(4)PcMg is more active than (t-Bu)(4)PcFe. But (t-Bu)(4)PcCo and (t-Bu)(4)PcNi only have low catalytic activities towards the reaction. Moreover, the yield will increase as the temperature increases.

引用

页码：1047 / 1050

页数：4

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