Selective reactions over solid base catalysts

被引：220
作者：
Ono, Y
Baba, T
机构：
[1] Department of Chemical Engineering, Tokyo Institute of Technology, Tokyo 152, Ookayama, Meguro-ku
来源：
CATALYSIS TODAY | 1997年 / 38卷 / 03期
关键词：
base catalyst; solid base; organic synthesis;
D O I：
10.1016/S0920-5861(97)81502-5
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A variety of organic reactions are catalyzed in a very selective manner by base catalysts. Especially, solid bases offer convenient and environmentally-benin routes for organic synthesis. This review overviews the recent development on the catalysis by solid bases. The catalytic materials described are zeolites, modified zeolites, alkaline earth oxides, alkali metals on supports, KNH2 on alumina, KF on alumina, hydrotalcites and oxynitrides. Stress are also placed on novel reactions catalyzed by the solid bases. The reactions include isomerization of alkenes, reactions of alkynes, methylations, addition reactions, Knoevenagel condensations, reactions of silanes.
引用
收藏
页码：321 / 337
页数：17
相关论文
共 102 条
  • [31] FU ZH, 1993, CATAL LETT, V21, P41
  • [32] APPLICATION OF A NEW HYDROGENATED ALUMINOPHOSPHATE OXYNITRIDE (ALPON) AS A CATALYTIC SUPPORT FOR THE ONE-STEP SYNTHESIS OF METHYL ISOBUTYL KETONE FROM ACETONE
    GANDIA, LM
    MALM, R
    MARCHAND, R
    CONANEC, R
    LAURENT, Y
    MONTES, M
    [J]. APPLIED CATALYSIS A-GENERAL, 1994, 114 (01) : L1 - L7
  • [33] INFLUENCE OF NITROGEN-CONTENT OF A NEW ALUMINOPHOSPHATE OXYNITRIDE CATALYST - ALPON IN KNOEVENAGEL CONDENSATION
    GRANGE, P
    BASTIANS, P
    CONANEC, R
    MARCHAND, R
    LAURENT, Y
    [J]. APPLIED CATALYSIS A-GENERAL, 1994, 114 (02) : L191 - L196
  • [34] BASE-CATALYZED REACTIONS .17. THE KINETICS OF CARBANION-CATALYZED ISOMERIZATION OF BUTENES AND 1-PENTENE
    HAAG, WO
    PINES, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (02) : 387 - 391
  • [35] Double-bond isomerization of olefinic amines over potassium amide loaded on alumina
    Handa, H
    Baba, T
    Yamada, H
    Takahashi, T
    Ono, Y
    [J]. CATALYSIS LETTERS, 1997, 44 (1-2) : 119 - 121
  • [36] HANDA H, UNPUB J MOL CATAL
  • [37] HANDA H, UNPUB
  • [38] HATADA K, 1976, B CHEM SOC JPN, V51, P448
  • [39] BASE CATALYSIS BY ALKALI MODIFIED ZEOLITES .3. ALKYLATION WITH METHANOL
    HATHAWAY, PE
    DAVIS, ME
    [J]. JOURNAL OF CATALYSIS, 1989, 119 (02) : 497 - 507
  • [40] BASE CATALYSIS BY ALKALI-MODIFIED ZEOLITES .2. NATURE OF THE ACTIVE-SITE
    HATHAWAY, PE
    DAVIS, ME
    [J]. JOURNAL OF CATALYSIS, 1989, 116 (01) : 279 - 284
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