Study on the reaction of 6-alkoxy-tetrachloro-12H-dibenzo[d,g][1,3,2]-dioxaphosphocin-6-sulfides with DMSO

被引：0

作者：

Zhang, XM ^{[1
]}

Yang, DB ^{[1
]}

Wang, DQ ^{[1
]}

Chen, WY ^{[1
]}

机构：

[1] China Agr Univ, Dept Appl Chem, Beijing 100094, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 22卷 / 10期

关键词：

6-alkoxy-2,4,8,10-tetrachloro-12H-dibenzo[d,g][1,3,2]dioxaphosphocin-6-sulfide; DMSO; reaction; molecular complex of 6-hydroxy-2,4,8,10-tetrachloro-12H-dibenzo[d,g][1,3,2]dioxaphosphocin-6-oxide center dot DMSO;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new molecular complex of 6-hydroxy-2,4,8,10-tetrachloro-12H-dibenzo [d, g] [1, 3, 2]-dioxaphosphocin-6-oxide.DMSO (1 : 1) (3) was obtained by the reaction of 6-alkoxy-2,4,8,10-tetrachloro-12H-dibenzo-[d,g] [1,3,2] dioxaphosphocin-6-sulfide (2) with excess DMSO. This reaction includes two steps: hydrolysis and oxidation. The hydrolytic intermediate (M) Was confirmed by P-31 NMR.

引用

页码：793 / 796

页数：4

共 8 条

[1]

Chen K, 2001, CHINESE J ORG CHEM, V21, P690

[2]

CHEN WY, 2000, CHINESE J PESTIC SCI, V2, P7

[3] 12H-DIBENZO[D,G][1,3,2]DIOXAPHOSPHOCINS - SYNTHESIS, STRUCTURES AND THROUGH-SPACE SPIN-SPIN COUPLING IN THEIR NMR-SPECTRA [J].

GODDARD, JD ;

PAYNE, AW ;

COOK, N ;

LUSS, HR .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1988, 25 (02) :575-588

[4]

MIKOLAJC.M, 1966, CHEM IND-LONDON, P2059

[5]

MIKOTAJCZYK M, 1974, CHEM IND, P70

[6] THE STEREOCHEMISTRY OF REACTION OF P-CHIRAL DIALKYL HYDROGEN PHOSPHOROTHIOATES WITH [O-18]-DIMETHYL SULFOXIDE [J].

OKRUSZEK, A ;

STEC, WJ .

TETRAHEDRON LETTERS, 1982, 23 (49) :5203-5206

[7] Synthesis of 6-aryloxy- and 6-p-tolylthioxy-2,10-dichloro-12-trichloromethyl-12H-dibenzo[d,g][1,3,2]dioxaphosphocin 6-oxides - X-ray diffraction analyses of 6-(4'-chlorophenoxy)-2,10-dichloro-12-trichloromethyl-12H-dibenzo[d,g][1,3,2]dioxaphosphocin 6-oxide and triethylammonium 2-methylphenyl 2-[{2',2',2'-trichloro-1'-(2''-hydroxyl-5''-chlorophenyl)}ethyl]-4-chlorophenyl phosphate [J].

Reddy, CD ;

Reddy, BS ;

Reddy, PM ;

Berlin, KD ;

Couch, KM ;

Tyagi, S ;

Hossain, MB ;

VanderHelm, D .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1996, 115 :149-160

[8]

STEPHEN SD, 1983, J HETEROCYCLIC CHEM, V20, P1311

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