Synthesis and electropolymerization of N-(4′-carboxyphenyl)-2,5-di(2"-thienyl)pyrrole

被引：22

作者：

Lengkeek, Nigel A. ^{[1
]}

Harrowfield, Jack M. ^{[2
]}

Koutsantonis, George A. ^{[1
]}

机构：

[1] Univ Western Australia, Sch Biomed Biomol & Chem Sci, Perth, WA 6009, Australia

[2] Univ Strasbourg, Inst Sci Ingenierie Supramol, F-67083 Strasbourg, France

来源：

SYNTHETIC METALS | 2010年 / 160卷 / 1-2期

关键词：

Dithienylpyrroles; Electropolymerization; Electrodeposition; Polymer-modified electrode; THIOPHENE OLIGOMERS; UV/VIS SPECTRA; ELECTROCATALYSIS; POLYMERS;

D O I：

10.1016/j.synthmet.2009.09.035

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

N-(4'-carboxyphenyl)-2,5-di(2 ''-thienyl)pyrrole has been efficiently prepared by the Knorr-Paal condensation of 1,4-di(2'-thienyl)butane-1,4-dione with benzocaine(ethyl-4-aminobenzoate), giving N(ethyl-4'-benzoate)-2,5-di(2 ''-thienyl)pyrrole, followed by saponification to give the desired acid. Both new compounds are electropolymerizable, and the polymer films stable to repetitive cycling up to +1.2 V Vs Ag/AgCl. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：72 / 75

页数：4

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