Rapid Synthesis of D-A′-π-A Dyes through a One-Pot Three-Component Suzuki-Miyaura Coupling and an Evaluation of their Photovoltaic Properties for Use in Dye-Sensitized Solar Cells

被引：20

作者：

Irie, Shunsuke ^{[1
]}

Fuse, Shinichiro ^{[1
,2
]}

Maitani, Masato M. ^{[1
]}

Wada, Yuji ^{[1
]}

Ogomi, Yuhei ^{[3
]}

Hayase, Shuzi ^{[3
]}

Kaiho, Tatsuo ^{[4
]}

Masui, Hisashi ^{[5
]}

Tanaka, Hiroshi ^{[1
]}

Takahashi, Takashi ^{[5
]}

机构：

[1] Tokyo Inst Technol, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan

[2] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

[3] Kyushu Inst Technol, Grad Sch Life Sci & Syst Engn, Fukuoka 8080196, Japan

[4] Kanto Nat Gas Dev Co Ltd, Brine Resources Res & Dev Div, Chiba 2978550, Japan

[5] Yokohama Univ Pharm, Totsuka Ku, Yokohama, Kanagawa 2450066, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 07期

关键词：

combinatorial chemistry; cross-coupling; dyes; pigments; solar cells; one-pot reactions; UNSYMMETRICAL SQUARAINE DYES; NANOCRYSTALLINE TIO2 FILMS; ORGANIC-DYES; MOLECULAR DESIGN; EFFICIENCY; ABSORPTION; HALIDES; ARYL; CONVERSION; CATALYSTS;

D O I：

10.1002/chem.201504277

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Twenty-four D-A--A dyes were rapidly synthesized through a one-pot three-component Suzuki-Miyaura coupling reaction, which was assisted by microwave irradiation. We measured the absorption spectra, electrochemical properties, and solar-cell performance of all the synthesized dyes. The D5A4 dye contained our originally designed rigid and nonplanar donor and exerted the highest efficiency at 5.4%. The short-circuit current (J(sc)) was the most important parameter for the conversion efficiency () in the case of the organic D-A--A dyes. Optimal ranges for the D-A--A dyes were observed for high values of J(sc)/(max) at =560-620nm, an optical-absorption edge of =690-790nm, and E-HOMO and E-LUMO values of <1.14 and -0.56 to -0.76V, respectively.

引用

页码：2507 / 2514

页数：8

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