Delicate substituent effect of isophthalate tectons on the structural assembly of diverse 4-connected metal-organic frameworks (MOFs)

被引：76

作者：

Ma, Lu-Fang ^{[1
,2
]}

Wang, Yao-Yu ^{[1
]}

Liu, Jian-Qiang ^{[1
]}

Yang, Guo-Ping ^{[1
]}

Du, Miao ^{[3
]}

Wang, Li-Ya ^{[2
]}

机构：

[1] NW Univ Xian, Shaanxi Key Lab Physicoinorgan Chem, Dept Chem, Minist Educ,Key Lab Synthet & Nat Funct Mol Chem, Xian 710069, Peoples R China

[2] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China

[3] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300387, Peoples R China

来源：

CRYSTENGCOMM | 2009年 / 11卷 / 09期

基金：

中国国家自然科学基金;

关键词：

II COORDINATION POLYMERS; PHYSICAL-PROPERTIES; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; MIXED-LIGANDS; POLYROTAXANE; NETWORK; DESIGN; TOPOLOGY; MOTIFS;

D O I：

10.1039/b904977k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Assembly of isophthalate derivatives with Zn-II in the presence of a flexible ligand 1,3-bis(4-pyridyl)propane yields distinct 4-connected coordination frameworks of sql (3.8(5))(3(2).8(3).9) and dia topologies, which reveal the delicate substituent effect of isophthalate tectons. The 3-D network in complex 2 is of 4-fold interpenetration with a new topology, displaying a unique polyrotaxane and polycatenane character.

引用

页码：1800 / 1802

页数：3

共 56 条

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