Silicon nanowires used as the anode of a lithium-ion battery

被引：5

作者：

Prosini, Pier Paolo ^{[1
,2
]}

Rufoloni, Alessandro ^{[3
]}

Rondino, Flaminia ^{[3
]}

Santoni, Antonino ^{[3
]}

机构：

[1] Italian Natl Agcy New Technol Energy & Sustainabl, ENEA, Casaccia Res Ctr, I-00123 Rome, Italy

[2] DInESto, Drive Innovat Energy Storage, I-04012 Cisterna Latina, Italy

[3] Italian Natl Agcy New Technol Energy & Sustainabl, ENEA, Frascati Res Ctr, I-00044 Frascati, Italy

来源：

NANOFORUM 2014 | 2015年 / 1667卷

关键词：

Silicon nanowires; Anode material; Lithium-ion battery; Chemical Vapor Deposition; Vapor-Liquid-Solid mechanism; NEGATIVE ELECTRODE; HIGH-CAPACITY; LINI0.5MN1.5O4; CATHODE; LIFEPO4; PERFORMANCE; LITHIATION; PARTICLES;

D O I：

10.1063/1.4922564

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

In this paper the synthesis and characterization of silicon nanowires to be used as the anode of a lithium-ion battery cell are reported. The nanowires were synthesized by CVD and characterized by SEM. The nanostructured material was used as an electrode in a lithium cell and its electrochemical properties were investigated by galvanostatic charge/discharge cycles at C/10 rate as a function of the cycle number and at various rates as a function of the charge current. The electrode was then coupled with a LiFePO4 cathode to fabricate a lithium-ion battery cell and the cell performance evaluated by galvanostatic charge/discharge cycles.

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页数：7

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共 23 条

[1] High-performance lithium battery anodes using silicon nanowires [J].

Chan, Candace K. ;

Peng, Hailin ;

Liu, Gao ;

McIlwrath, Kevin ;

Zhang, Xiao Feng ;

Huggins, Robert A. ;

Cui, Yi .

NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35

[2] Enhanced reversible lithium storage in a nanosize silicon/graphene composite [J].

Chou, Shu-Lei ;

Wang, Jia-Zhao ;

Choucair, Mohammad ;

Liu, Hua-Kun ;

Stride, John A. ;

Dou, Shi-Xue .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (02) :303-306

[3] Crystalline-Amorphous Core-Shell Silicon Nanowires for High Capacity and High Current Battery Electrodes [J].

Cui, Li-Feng ;

Ruffo, Riccardo ;

Chan, Candace K. ;

Peng, Hailin ;

Cui, Yi .

NANO LETTERS, 2009, 9 (01) :491-495

[4] Correlation between irreversible capacity and electrolyte solvents degradation probed by NMR in Si-based negative electrode of Li-ion cell [J].

Delpuech, N. ;

Dupre, N. ;

Mazouzi, D. ;

Gaubicher, J. ;

Moreau, P. ;

Bridel, J. S. ;

Guyomard, D. ;

Lestriez, B. .

ELECTROCHEMISTRY COMMUNICATIONS, 2013, 33 :72-75

[5] Surface chemistry of carbon-treated LiFePO4 particles for Li-ion battery cathodes studied by PES [J].

Herstedt, M ;

Stjerndahl, M ;

Nytén, A ;

Gustafsson, T ;

Rensmo, H ;

Siegbahn, H ;

Ravet, N ;

Armand, M ;

Thomas, JO ;

Edström, K .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (09) :A202-A206

[6] Amorphous silicon anode for lithium-ion rechargeable batteries [J].

Jung, HJ ;

Park, M ;

Yoon, YG ;

Kim, GB ;

Joo, SK .

JOURNAL OF POWER SOURCES, 2003, 115 (02) :346-351

[7] Improving the rate capability of high voltage lithium-ion battery cathode material LiNi0.5Mn1.5O4 by ruthenium doping [J].

Kiziltas-Yavuz, Niluefer ;

Bhaskar, Aiswarya ;

Dixon, Ditty ;

Yavuz, Murat ;

Nikolowski, Kristian ;

Lu, Li ;

Eichel, Ruediger-A. ;

Ehrenberg, Helmut .

JOURNAL OF POWER SOURCES, 2014, 267 :533-541

[8] Higher, Stronger, Better ... A Review of 5 Volt Cathode Materials for Advanced Lithium-Ion Batteries [J].

Kraytsberg, Alexander ;

Ein-Eli, Yair .

ADVANCED ENERGY MATERIALS, 2012, 2 (08) :922-939

[9] Effect of nano LiFePO4 coating on LiMn1.5Ni0.5O4 5V cathode for lithium ion batteries [J].

Liu, D. ;

Trottier, J. ;

Charest, P. ;

Frechette, J. ;

Guerfi, A. ;

Mauger, A. ;

Julien, C. M. ;

Zaghib, K. .

JOURNAL OF POWER SOURCES, 2012, 204 :127-132

[10] Spinel LiNi0.5Mn1.5O4 and its derivatives as cathodes for high-voltage Li-ion batteries [J].

Liu, G. Q. ;

Wen, L. ;

Liu, Y. M. .

JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2010, 14 (12) :2191-2202