EXAFS of liquid As-Te mixtures

被引:2
作者
Miyanaga, T
Hoshino, H
Ikemoto, H
Yuza, M
Yamamoto, I
Endo, H
机构
[1] HIROSAKI UNIV,FAC EDUC,HIROSAKI,AOMORI 036,JAPAN
[2] TOYAMA UNIV,FAC SCI,TOYAMA 930,JAPAN
[3] FUKUI INST TECHNOL,FAC ENGN,FUKUI 910,JAPAN
来源
JOURNAL DE PHYSIQUE IV | 1997年 / 7卷 / C2期
关键词
D O I
10.1051/jp4:19972115
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The EXAFS measurements on As and Te K-edges of liquid As2Te3 have been carried out in the temperature range including the supercooled liquid state down to 330 degrees C. By curve-fitting analyses with two-shell model the bond lengths and the coordination numbers were determined. It is suggested that As atoms within a chain bridge neighbouring chains with decreasing temperature and the network structure with three-fold coordinated As and two-fold coordinated Te is formed near the glass transition temperature.
引用
收藏
页码:1001 / 1002
页数:2
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