A "Cyanine-Cyanine" Salt Exhibiting Photovoltaic Properties

被引:70
作者
Bouit, Pierre-Antoine [1 ,2 ]
Rauh, Daniel [3 ]
Neugebauer, Stefan [4 ]
Luis Delgado, Juan [2 ,6 ]
Di Piazza, Emmanuel [5 ]
Rigaut, Stephane [5 ]
Maury, Olivier [1 ]
Andraud, Chantal [1 ]
Dyakonov, Vladimir [3 ,4 ]
Martin, Nazario [2 ,6 ]
机构
[1] Univ Lyon, Chim Lab, Ecole Normale Super Lyon, CNRS,UMR 5182, F-69007 Lyon, France
[2] IMDEA Nanociencia, Fac Ciencias, Madrid 28049, Spain
[3] Bavarian Ctr Appl Energy Res ZAE Bayern, D-97074 Wurzburg, Germany
[4] Univ Wurzburg, D-97074 Wurzburg, Germany
[5] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France
[6] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Organ, E-28040 Madrid, Spain
关键词
ORGANIC PHOTOVOLTAICS; SOLAR-CELLS; DYES; PERFORMANCE; DONOR;
D O I
10.1021/ol901764t
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Association between cationic and anionic heptamethine dyes led to the formation of a new organic salt (3) displaying exceptional light-harvesting properties in the NIR spectral range and having amphoteric redox character. Preliminary results of molecular bulk heterojunction solar cells based on the title compound 3 and [60]PCBM as the only active layer reveal this new dye as a promising light-harvesting material for photovoltaics.
引用
收藏
页码:4806 / 4809
页数:4
相关论文
共 21 条
[1]   High efficiency organic photovoltaics incorporating a new family of soluble fullerene derivatives [J].
Backer, Scott A. ;
Sivula, Kevin ;
Kavulak, David F. ;
Frechet, Jean M. J. .
CHEMISTRY OF MATERIALS, 2007, 19 (12) :2927-2929
[2]   Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor [J].
Beverina, L ;
Fu, J ;
Leclercq, A ;
Zojer, E ;
Pacher, P ;
Barlow, S ;
Van Stryland, EW ;
Hagan, DJ ;
Brédas, JL ;
Marder, SR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (20) :7282-7283
[3]   Stable near-infrared anionic polymethine dyes: Structure, photophysical, and redox properties [J].
Bouit, Pierre-Antoine ;
Di Piazza, Emmanuel ;
Rigaut, Stephane ;
Le Guennic, Boris ;
Aronica, Christophe ;
Toupet, Loic ;
Andraud, Chantal ;
Maury, Olivier .
ORGANIC LETTERS, 2008, 10 (19) :4159-4162
[4]   Near IR nonlinear absorbing chromophores with optical limiting properties at telecommunication wavelengths [J].
Bouit, Pierre-Antoine ;
Wetzel, Guillaume ;
Berginc, Gerard ;
Loiseaux, Brigitte ;
Toupet, Loic ;
Feneyrou, Patrick ;
Bretonniere, Yann ;
Kamada, Kenji ;
Maury, Olivier ;
Andraud, Chantal .
CHEMISTRY OF MATERIALS, 2007, 19 (22) :5325-5335
[5]   Novel water-soluble near-infrared cyanine dyes:: Synthesis, spectral properties, and use in the preparation of internally quenched fluorescent probes [J].
Bouteiller, Cedric ;
Clave, Guillaume ;
Bernardin, Aude ;
Chipon, Bertrand ;
Massonneau, Marc ;
Renard, Pierre-Yves ;
Romieu, Anthony .
BIOCONJUGATE CHEMISTRY, 2007, 18 (04) :1303-1317
[6]   On the use of cyanine dyes as low-bandgap materials in bulk heterojunction photovoltaic devices [J].
Castro, Fernando A. ;
Faes, Antonin ;
Geiger, Thomas ;
Graeff, Carlos F. O. ;
Nagel, Matthias ;
Nueesch, Frank ;
Hany, Roland .
SYNTHETIC METALS, 2006, 156 (14-15) :973-978
[7]   Enhanced cyanine solar cell performance upon oxygen doping [J].
Fan, Bin ;
Hany, Roland ;
Moser, Jacques-Edouard ;
Nueesch, Frank .
ORGANIC ELECTRONICS, 2008, 9 (01) :85-94
[8]   Near-infrared-emissive polymersomes:: Self-assembled soft matter for in vivo optical imaging [J].
Ghoroghchian, PP ;
Frail, PR ;
Susumu, K ;
Blessington, D ;
Brannan, AK ;
Bates, FS ;
Chance, B ;
Hammer, DA ;
Therien, MJ .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2005, 102 (08) :2922-2927
[9]   Bulk heterojunction organic solar cells based on merocyanine colorants [J].
Kronenberg, Nils M. ;
Deppisch, Manuela ;
Wuerthner, Frank ;
Lademann, Hans W. A. ;
Deing, Kaja ;
Meerholz, Klaus .
CHEMICAL COMMUNICATIONS, 2008, (48) :6489-6491
[10]   High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends [J].
Li, G ;
Shrotriya, V ;
Huang, JS ;
Yao, Y ;
Moriarty, T ;
Emery, K ;
Yang, Y .
NATURE MATERIALS, 2005, 4 (11) :864-868