Oxidation of alcohols using RuMnCe catalysts

被引：8

作者：

Checinski, Marek Pawel ^{[1
]}

Brueckner, Angelika ^{[1
]}

Radnik, Joerg ^{[1
]}

Koeckritz, Angela ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, Branch Berlin, D-12489 Berlin, Germany

来源：

APPLIED CATALYSIS A-GENERAL | 2009年 / 366卷 / 01期

关键词：

Alcohols; Aldehydes; Ketones; Catalytic oxidation; Molecular oxygen; Heterogeneous RuMnCe catalysts; LIQUID-PHASE OXIDATION; SELECTIVE OXIDATION; AEROBIC OXIDATION; CARBONYL-COMPOUNDS; MOLECULAR-OXYGEN; HETEROGENEOUS OXIDATION; ALDEHYDES; OXIDE; EFFICIENT; DIOXIDE;

D O I：

10.1016/j.apcata.2009.07.007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The combination of ruthenium, manganese as well as cerium oxides formed an active catalytic system for the oxidation of 2-octanol and other alcohols. The addition of manganese species as promotors resulted in more active catalysts than comparable cobalt-doped oxidic materials. The application of RuMnCe oxides on redox-active supports, such as TiO2 or CeO2, by deposition-precipitation caused a further improvement of catalytic activity. A tolerance to nitrogen-containing substrates was observed. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：212 / 219

页数：8

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