Modification and characterization of maleic anhydride-styrene-methyl metacrylate terpolymer using various alcohols

被引:4
作者
Boztug, Ali [1 ]
Basan, Satilmis
机构
[1] Cumhuriyet Univ, Dept Chem, TR-58140 Sivas, Turkey
[2] Gazi Univ, Fac Engn, Corum, Turkey
关键词
maleic anhydride; terpolymer; stress; strain; esterification;
D O I
10.1163/156855506778944046
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this Study, the anhydride units in maleic anhydride-styrene-methyl metacrylate terpolymer (MA-St-MMA) were reacted with n-propyl, n-butyl, n-pentyl and n-benzyl alcohols, and the ester derivatives of MA-St-MMA terpolymer were obtained. These were named n-alkyl maleate ester derivatives, abbreviated as nPrMA-St-MMA, nBuMA-St-MMA, nPnMA-St-MMA and nBzMA-St-MMA. The aim of this Study was to obtain more elastic polymers by replacement with the maleic anhydride Units in MA-St-MMA terpolymer of alkyl groups having a linear chain structure. All the polymers synthesized were characterized by FT-IR, TMA, the solvent definition, the number of esters and solution viscosity. The TMA experiments of all the polymers were studied under increasing and temperature. All these Studies have showed that the n-alkyl maleate ester derivatives are more elastic than original MA-St-MMA terpolymer.
引用
收藏
页码:617 / 626
页数:10
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