共 51 条
One-pot synthesis of ABC type triblock copolymers via in situ click [3+2] and Diels-Alder [4+2] reactions
被引:204
作者:

Durmaz, Hakan
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Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

Dag, Aydan
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Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

Altintas, Ozcan
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Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

Erdogan, Tuba
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Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

Hizal, Gurkan
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Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

Tunca, Umit
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机构:
Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey
机构:
[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey
关键词:
D O I:
10.1021/ma061819l
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
We report a one-pot synthesis of ABC triblock copolymers of poly(ethylene glycol)- (PEG-) polystyrene- (PS-) poly(methyl methacrylate) (PMMA), and poly(epsilon-caprolactone)- (PCL-) PS-PMMA by combining in situ click [3 + 2] and Diels-Alder [4 + 2] reactions. For this purpose, furan-protected maleimide end-functionalized PMMA, PS with alpha-anthracene and omega-azide end-functionality, and PEG or PCL with an alkyne end-functional group were reacted in N,N-dimehtylformamide (DMF) for 36 h at 120 degrees C in order to give the corresponding triblock copolymers. All polymeric precursors with narrow molecular weight distribution and well-defined chain-end functionalities were achieved from living polymerization methods, except PEG. The obtained polymers were characterized by H-1 NMR (250 MHz), gel permeation chromatography (GPC), and differential scanning calorimetry (DSC) measurements.
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页码:191 / 198
页数:8
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