Mechanism of conduction in doped polyaniline

被引:41
作者
Campos, M [1 ]
Bello, B [1 ]
机构
[1] UNIV ESTADUAL SANTA CATARINA,FAC ENGN,DEPT ENGN MECAN,BR-89223100 JOINVILE,SC,BRAZIL
关键词
D O I
10.1088/0022-3727/30/10/021
中图分类号
O59 [应用物理学];
学科分类号
摘要
The conductivity of H2SiF6-doped emeraldine polymers is studied as a function of temperature in the range 50 less than or equal to T less than or equal to 180 K. The dopant concentration of the samples varies between 0.1 M and 1.0 M. The temperature dependence of the do electrical conductivity gives evidence for a transport mechanism based on variable-range hopping in three dimensions. Using Mott's formula for the de conductivity, physically meaningful values of the density of states at the Fermi energy, the hopping energy and hopping distance are calculated.
引用
收藏
页码:1531 / 1535
页数:5
相关论文
共 29 条
[1]  
ABELES B, 1975, ADV PHYS, V24, P407, DOI 10.1080/00018737500101431
[2]   POLYANILINE - SOLUTIONS, FILMS AND OXIDATION-STATE [J].
ANGELOPOULOS, M ;
ASTURIAS, GE ;
ERMER, SP ;
RAY, A ;
SCHERR, EM ;
MACDIARMID, AG ;
AKHTAR, M ;
KISS, Z ;
EPSTEIN, AJ .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1988, 160 :151-163
[3]   HIGHLY CONDUCTING POLYPARAPHENYLENE, POLYPYRROLE, AND POLYTHIOPHENE CHAINS - AN ABINITIO STUDY OF THE GEOMETRY AND ELECTRONIC-STRUCTURE MODIFICATIONS UPON DOPING [J].
BREDAS, JL ;
THEMANS, B ;
FRIPIAT, JG ;
ANDRE, JM ;
CHANCE, RR .
PHYSICAL REVIEW B, 1984, 29 (12) :6761-6773
[4]   ELECTRICAL-CONDUCTIVITY IN DOPED POLYACETYLENE [J].
CHIANG, CK ;
FINCHER, CR ;
PARK, YW ;
HEEGER, AJ ;
SHIRAKAWA, H ;
LOUIS, EJ ;
GAU, SC ;
MACDIARMID, AG .
PHYSICAL REVIEW LETTERS, 1977, 39 (17) :1098-1101
[5]   POLYANILINE - PROTONIC ACID DOPING OF THE EMERALDINE FORM TO THE METALLIC REGIME [J].
CHIANG, JC ;
MACDIARMID, AG .
SYNTHETIC METALS, 1986, 13 (1-3) :193-205
[6]   COMMENSURABILITY EFFECTS AND MODULATED STRUCTURE IN POLYANILINES [J].
CHOI, HY ;
MELE, EJ .
PHYSICAL REVIEW LETTERS, 1987, 59 (19) :2188-2191
[7]  
Davis E. A., 1979, ELECT PROCESSES NONC
[8]  
FOCKE WW, 1988, J ELECTROANAL CHEM, V256, P343
[9]   FREQUENCY-DEPENDENT CONDUCTIVITY IN POLYANILINE [J].
HAYASHI, T ;
HIRAI, Y ;
TANAKA, H ;
NISHI, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1987, 26 (11) :L1800-L1802
[10]   SIMULTANEOUS POLYMERIZATION AND FORMATION OF POLYACETYLENE FILM ON SURFACE OF CONCENTRATED SOLUBLE ZIEGLER-TYPE CATALYST SOLUTION [J].
ITO, T ;
SHIRAKAWA, H ;
IKEDA, S .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1974, 12 (01) :11-20