Preparation and cationic photopolymerization of organic-inorganic hybrid matrixes

被引：42
作者：
Crivello, JV
Mao, ZB
机构：
[1] Department of Chemistry, Rensselaer Polytechnic Institute, Troy
来源：
CHEMISTRY OF MATERIALS | 1997年 / 9卷 / 07期
关键词：
D O I：
10.1021/cm960595q
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Surface modifications of colloidal silica by sol-gel techniques with trialkoxysilane coupling agents bearing cationically polymerizable epoxy and 1-propenyl ether groups were carried out under mild conditions. After dilution with difunctional epoxy and 1-propenyl ether monomers and the addition of an onium salt photoinitiator, the mixtures were irradiated with UV light to provide organic-inorganic hybrid matrixes. Photopolymerizations were uniformly rapid and proceeded to high conversions. Colorless, transparent, cross-linked films potentially useful as abrasion resistant coatings for plastic articles were produced.
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页码：1562 / 1569
页数：8
相关论文
共 32 条
[1]   SILICA PARTICLES STABILIZED BY LONG GRAFTED POLYMER-CHAINS - FROM ELECTROSTATIC TO STERIC REPULSION [J].
AUROY, P ;
AUVRAY, L ;
LEGER, L .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1992, 150 (01) :187-194
[2]  
BRADLEY RD, 1990, LANGMUIR, V6, P792
[3]  
Crivello J.V., 1993, RING OPENING POLYM, P157
[4]   THE SYNTHESIS AND CATIONIC POLYMERIZATION OF MULTIFUNCTIONAL SILICON-CONTAINING EPOXY MONOMERS AND OLIGOMERS [J].
CRIVELLO, JV ;
BI, DS .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1994, 32 (04) :683-697
[5]  
CRIVELLO JV, 1991, J COATING TECHNOL, V63, P35
[6]   REGIOSELECTIVE HYDROSILATIONS .4. THE SYNTHESIS AND POLYMERIZATION OF MONOMERS CONTAINING EPOXY AND ALKOXYSILANE GROUPS [J].
CRIVELLO, JV ;
BI, DS .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (12) :3121-3132
[7]   THE SYNTHESIS, CHARACTERIZATION, AND PHOTOINITIATED CATIONIC POLYMERIZATION OF SILICON-CONTAINING EPOXY-RESINS [J].
CRIVELLO, JV ;
LEE, JL .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1990, 28 (03) :479-503
[8]   Synthesis and photopolymerization of 1-propenyl ether functional siloxanes [J].
Crivello, JV ;
Lohden, G .
CHEMISTRY OF MATERIALS, 1996, 8 (01) :209-218
[9]   ALKOXY-SUBSTITUTED DIARYLIODONIUM SALT CATIONIC PHOTOINITIATORS [J].
CRIVELLO, JV ;
LEE, JL .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (12) :3951-3968
[10]   CHEMOSELECTIVE HYDROSILATIONS .1. SYNTHESIS AND PHOTOPOLYMERIZATION OF 1-PROPENYL ETHER FUNCTIONALIZED SILOXANES [J].
CRIVELLO, JV ;
YANG, B ;
KIM, WG .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1995, 33 (14) :2415-2423
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