A novel 3D twofold interpenetrating microporous metal-organic framework containing 1D water tapes with cyclic pentamer units

被引：28
作者：
Liu, Jian-Qiang
Wang, Yao-Yu [1 ]
Liu, Ping
Wu, Wei-Ping
Wu, Ya-Pan
Zeng, Xi-Rui
Zhong, Fan
Shi, Qi-Zhen
机构：
[1] NW Univ Xian, Shaanxi Key Lab Physicoinorgan Chem, Dept Chem, Xian 710069, Peoples R China
[2] NW Univ Xian, Shaanxi Key Lab Physicoinorgan Chem, Dept Chem, Xian 710069, Peoples R China
[3] Jinggangshan Coll, Dept Chem, Jian 343009, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 03期
基金：
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词：
interpenetration; topology; pentamer cluster; crystal structure; copper(II) complex;
D O I：
10.1016/j.inoche.2006.11.003
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The self-assembly of Cu2+ ions with malate and 1,3-bis(4-pyridyl)propane (bpp) affords a 3D coordination polymer {[Cu(Hmal) (bpp) (.) 6H(2)O]}(n) (1) (malic acid = H(3)mal). The metal ions were interconnected by alpha- and beta-carboxylate of malate produce infinite [Cu(C4H4O5)](n) layers, which were further pillared by bridging ligand bpp molecules to form a 3D interpenetrating network. Of further interest, lattice water molecules form ID infinite water tapes in ID open cavities. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：343 / 347
页数：5
相关论文
共 44 条
[1]  
Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
[2]  
2-Z
[3]   Topology of interpenetration [J].
Batten, SR .
CRYSTENGCOMM, 2001, (18)
[4]   Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database [J].
Blatov, VA ;
Carlucci, L ;
Ciani, G ;
Proserpio, DM .
CRYSTENGCOMM, 2004, 6 :377-395
[5]   Infrared spectroscopy of size-selected water and methanol clusters [J].
Buck, U ;
Huisken, F .
CHEMICAL REVIEWS, 2000, 100 (11) :3863-3890
[6]  
BUCK U, 2000, CHEM COMMUN, P62
[7]  
CARBALLO R, 2006, CRYST GROWTH DES, V5, P226
[8]   An unprecedented triply interpenetrated chiral network of 'square-planar' metal centres from the self-assembly of copper(II) nitrate and 1,2-bis(4-pyridyl)ethyne [J].
Carlucci, L ;
Ciani, G ;
Macchi, P ;
Proserpio, DM .
CHEMICAL COMMUNICATIONS, 1998, (17) :1837-1838
[9]   New polymeric networks from the self-assembly of silver(I) salts and the flexible ligand 1,3-bis(4-pyridyl)propane (bpp). A systematic investigation of the effects of the counterions and a survey of the coordination polymers base on bpp [J].
Carlucci, L ;
Ciani, G ;
Proserpio, DM ;
Rizzato, S .
CRYSTENGCOMM, 2002, 4 (22) :121-129
[10]   Chiral packing of chiral quintuple layers polycatenated to give a three-dimensional network in the coordination polymer [Co5(bpe)9(H2O)8(SO4)4](SO4)•14H2O [bpe=1,2-bis(4-pyridyl)ethane] [J].
Carlucci, L ;
Ciani, G ;
Proserpio, DM ;
Rizzato, S .
CHEMICAL COMMUNICATIONS, 2000, (14) :1319-1320
12345