The study on the interface characteristics of solid-state electrolyte

被引:9
作者
Lim, Hyung-Sik [1 ]
Liu, Liyu [1 ]
Lee, Hyun-Joon [1 ]
Cha, Jae-Min [2 ]
Yoon, Duck-ki [3 ]
Ryu, Bong-Ki [1 ]
机构
[1] Pusan Natl Univ, Dept Mat Sci & Engn, Busan 46241, South Korea
[2] Pusan Natl Univ, Inst Mat Technol, Busan 46241, South Korea
[3] Jeong Kwan Display Co Ltd, R&D Ctr, Gyeongsangnam Do 50581, South Korea
关键词
All-solid-state lithium batteries; Solid electrolyte; Interfacial reaction;
D O I
10.1007/s43207-021-00110-y
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Solid electrolytes for all-solid-state lithium batteries are excellent in terms of stability, and their performance has been improved through many studies. However, due to the interfacial reaction with lithium and sold electrolyte, there is a problem that the performance is deteriorated when used for a long time. In this study, the charge/discharge evaluation of more than 50 cycles was conducted and we analyzed the change Ti4+ to Ti3+ in the solid electrolyte using X-ray photoelectron spectroscopy. Finally, it was confirmed that the performance of the LiNbO3-coated solid electrolyte did not decrease even after long-term use.
引用
收藏
页码:373 / 377
页数:5
相关论文
共 50 条
[31]   Advancing solid-state lithium phosphate electrolyte: Synthesis and characterization of Li2NaPO4-ZrO2 nanocomposites for solid-state batteries [J].
Parbin, Abjana ;
Rafiuddin .
JOURNAL OF SOLID STATE CHEMISTRY, 2024, 332
[32]   Solid Electrolyte For Solid-State Batteries: Have lithium-ion batteries reached their technical limit? [J].
Kartini, Evvy ;
Manawan, Maykel .
6TH NANOSCIENCE AND NANOTECHNOLOGY SYMPOSIUM (NNS2015), 2016, 1710
[33]   Electrochemical properties of Li symmetric solid-state cell with NASICON-type solid electrolyte and electrodes [J].
Kobayashi, Eiji ;
Plashnitsa, Larisa S. ;
Doi, Takayuki ;
Okada, Shigeto ;
Yamaki, Jun-ichi .
ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (07) :894-896
[34]   Sensing behavior of solid-state impedancemetric NOx sensor using solid electrolyte transducer and oxide receptor [J].
Cho, Hong-Chan ;
Takase, Satoko ;
Song, Jeong-Hwan ;
Shimizu, Youichi .
SENSORS AND ACTUATORS B-CHEMICAL, 2013, 187 :94-98
[35]   Non-Resonant Structure Induces N-Rich Solid Electrolyte Interface toward Ultra-Stable Solid-State Lithium-Metal Batteries [J].
Zhang, Shuoxiao ;
Liu, Han ;
Liu, Zhengbo ;
Zhao, Yajun ;
Yan, Jie ;
Zhang, Yangqian ;
Liu, Fangyan ;
Liu, Qi ;
Liu, Chen ;
Sun, Gang ;
Wang, Zhenbo ;
Yang, Jiayi ;
Ren, Yang .
ADVANCED FUNCTIONAL MATERIALS, 2024, 34 (36)
[36]   Improved performance of solid-state metal hydride batteries using heteropolyacid hydrate as an electrolyte [J].
Hatakeyama, K ;
Sakaguchi, H ;
Yamaguchi, T ;
Inoue, H ;
Iwakura, C ;
Esaka, T .
ELECTROCHEMISTRY, 2004, 72 (10) :697-699
[37]   Anharmonicity and the emergence of diffusive behavior in a lattice-solute model solid-state electrolyte [J].
Beg, Cameran ;
Kieffer, John .
COMPUTATIONAL MATERIALS SCIENCE, 2023, 228
[38]   Study of lithium glassy solid electrolyte/electrode interface by impedance analysis [J].
Karthikeyan, A ;
Vinatier, P ;
Levasseur, A .
BULLETIN OF MATERIALS SCIENCE, 2000, 23 (03) :179-183
[39]   Development and Research Process of Ultra-Thin Sulfide Solid-State Electrolyte Film [J].
Yu, Canwen ;
Liu, Xinyi ;
Zhang, Baisong ;
Jiang, Yidong ;
Deng, Yonghong ;
Xu, Xiaoxiong ;
Chi, Shangsen .
Kuei Suan Jen Hsueh Pao/Journal of the Chinese Ceramic Society, 2025, 53 (06) :1577-1599
[40]   Room-temperature-operating Na solid-state battery with complex hydride as electrolyte [J].
Murgia, Fabrizio ;
Brighi, Matteo ;
Cerny, Radovan .
ELECTROCHEMISTRY COMMUNICATIONS, 2019, 106