The study on the interface characteristics of solid-state electrolyte

被引:9
作者
Lim, Hyung-Sik [1 ]
Liu, Liyu [1 ]
Lee, Hyun-Joon [1 ]
Cha, Jae-Min [2 ]
Yoon, Duck-ki [3 ]
Ryu, Bong-Ki [1 ]
机构
[1] Pusan Natl Univ, Dept Mat Sci & Engn, Busan 46241, South Korea
[2] Pusan Natl Univ, Inst Mat Technol, Busan 46241, South Korea
[3] Jeong Kwan Display Co Ltd, R&D Ctr, Gyeongsangnam Do 50581, South Korea
关键词
All-solid-state lithium batteries; Solid electrolyte; Interfacial reaction;
D O I
10.1007/s43207-021-00110-y
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Solid electrolytes for all-solid-state lithium batteries are excellent in terms of stability, and their performance has been improved through many studies. However, due to the interfacial reaction with lithium and sold electrolyte, there is a problem that the performance is deteriorated when used for a long time. In this study, the charge/discharge evaluation of more than 50 cycles was conducted and we analyzed the change Ti4+ to Ti3+ in the solid electrolyte using X-ray photoelectron spectroscopy. Finally, it was confirmed that the performance of the LiNbO3-coated solid electrolyte did not decrease even after long-term use.
引用
收藏
页码:373 / 377
页数:5
相关论文
共 15 条
[1]   Lithium-ion transfer at the interface between lithium-ion conductive ceramic electrolyte and liquid electrolyte - A key to enhancing the rate capability of lithium-ion batteries [J].
Abe, T ;
Sagane, F ;
Ohtsuka, M ;
Iriyama, Y ;
Ogumi, Z .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (11) :A2151-A2154
[2]  
Atkin, 2006, INORG CHEM, P729
[3]   A high-rate, long-life, lithium nanocomposite polymer electrolyte battery [J].
Croce, F ;
Fiory, FS ;
Persi, L ;
Scrosati, B .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (08) :A121-A123
[4]   Ceramic and polymeric solid electrolytes for lithium-ion batteries [J].
Fergus, Jeffrey W. .
JOURNAL OF POWER SOURCES, 2010, 195 (15) :4554-4569
[5]   Degradation of NASICON-Type Materials in Contact with Lithium Metal: Formation of Mixed Conducting Interphases (MCI) on Solid Electrolytes [J].
Hartmann, Pascal ;
Leichtweiss, Thomas ;
Busche, Martin R. ;
Schneider, Meike ;
Reich, Marisa ;
Sann, Joachim ;
Adelhelm, Philipp ;
Janek, Juergen .
JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (41) :21064-21074
[6]   Formation of electrode-electrolyte interface by lithium insertion to SnS-P2S5 negative electrode materials in all-solid-state cells [J].
Hayashi, Akitoshi ;
Konishi, Takanori ;
Tadanaga, Kiyoharu ;
Tatsumisago, Masahiro .
SOLID STATE IONICS, 2006, 177 (26-32) :2737-2740
[7]  
Kang B., 2018, Ceramist, V21, P349, DOI [10.31613/ceramist.2018.21.4.04, DOI 10.31613/CERAMIST.2018.21.4.04]
[8]   Lithium-ion conductive glass-ceramics with composition ratio control and their electrochemical characteristics [J].
Katoh, Takashi ;
Inda, Yasushi ;
Baba, Mamoru ;
Ye, Rongbin .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2010, 118 (1384) :1159-1162
[9]   Inorganic solid Li ion conductors: An overview [J].
Knauth, Philippe .
SOLID STATE IONICS, 2009, 180 (14-16) :911-916
[10]   Composite electrolytes of pyrrolidone-derivatives-PEO enable to enhance performance of all solid state lithium-ion batteries [J].
Li, Xin ;
Wang, Zijian ;
Lin, Hai ;
Liu, Yidong ;
Min, Yong ;
Pan, Feng .
ELECTROCHIMICA ACTA, 2019, 293 :25-29