Molecular ladders with multiple interpenetration of the lateral arms into the squares of adjacent ladders observed for [M2(4,4′-bpy)3(H2O)2(phba)2](NO3)2•4H2O (M = Cu2+ or Co2+; 4,4′-bpy=4,4′-bipyridine; phba=4-hydroxybenzoate)

被引:191
作者
Tong, ML [1 ]
Chen, HJ [1 ]
Chen, XM [1 ]
机构
[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
关键词
D O I
10.1021/ic991312+
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
isomorphous molecular ladders formulated as [M-2- (4,4'-bpy)(3)(phba)(2)(H2O)(2)](NO3)(2). 4H(2)O (4,4'-bpy = 4,4'-bipyridine; phba = 4-hydroxybenzoate; M = Cu2+ Or Co2+), shown by X-ray, feature a novel ladder motif having different inner rungs (4,4'-bpy) and lateral arms (phba). Penetration of the lateral arms into the squares of adjacent ladders results in a novel 3-D network.
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页码:2235 / +
页数:5
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