Statistical mechanics of dissipative transport in crystals

被引:18
作者
Szamel, G
机构
[1] Department of Chemistry, Colorado State University, Fort Collins
关键词
statistical mechanics; nonequilibrium statistical mechanics; crystals; slow (hydrodynamic and broken symmetry) modes; transport coefficients; FLUIDS;
D O I
10.1007/BF02181271
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We present a microscopic derivation of dissipative (nonideal) hydrodynamic-like equations for crystals. The local density changes and the lattice displacement (distortion) are treated as independent. In this way we take into account all the eight slow modes predicted by the phenomenological theory, including the so-called vacancy diffusion mode. However, microscopically derived hydrodynamic-like equations are simpler than those postulated in the phenomenological theory. We also derive the exact formal expressions for the solid-state transport coefficients in terms of the Green-Kubo integrals.
引用
收藏
页码:1067 / 1082
页数:16
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