Ammonia borane, a material with exceptional properties for chemical hydrogen storage

被引：247

作者：

Demirci, Umit B. ^{[1
]}

机构：

[1] Univ Montpellier, IEM, CNRS,ENSCM,UM, UMR 5635, Pl E Bataillon, F-34095 Montpellier, France

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2017年 / 42卷 / 15期

关键词：

Ammonia borane; Fundamentals; Hydrogen storage; Hydrolysis; Thermolysis; CORE-SHELL NANOPARTICLES; METAL-ORGANIC FRAMEWORK; MONODISPERSE RUTHENIUM NANOPARTICLES; INTERNAL-ROTATION BARRIER; SOLID-STATE THERMOLYSIS; LARGE-SCALE SYNTHESIS; THERMAL-DECOMPOSITION; AB-INITIO; HYDROLYTIC DEHYDROGENATION; HIGHLY EFFICIENT;

D O I：

10.1016/j.ijhydene.2017.01.154

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ammonia borane H3N-BH3, first reported in 1955, is isoelectronic with ethane H3C-CH3, but it has much different properties owing to (i) the nitrogen and boron atoms (leading to a dipole moment), (ii) the protic and hydridic hydrogens, and (iii) the heteropolar dihydrogen bonding (rationalizing its solid state at ambient conditions). Ammonia borane has exceptional properties for chemical hydrogen storage and the recent years have witnessed many efforts in making it implementable for both thermolytic and hydrolytic dehydrogenations. The present article aims at (1) giving an exhaustive overview of the 1955-2016 literature dedicated to ammonia borane's fundamentals and exceptional properties, and then (2) surveying the main achievements, limitations and challenges for chemical hydrogen storage. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：9978 / 10013

页数：36

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