Microwave-absorbing characteristics of epoxy resin composites containing nanoparticles of NiZn- and NiCuZn-ferrites

被引:93
作者
Aphesteguy, J. C. [1 ]
Damiani, Abel [2 ]
DiGiovanni, Dalmas [2 ]
Jacobo, S. E. [1 ]
机构
[1] Univ Buenos Aires, Fac Ingn, Dept Quim, RA-1063 Buenos Aires, DF, Argentina
[2] CITEFA, Div Antenas & Propagac, Buenos Aires, DF, Argentina
关键词
Composites; Magnetic nanoparticles; Ferrites; Microwave absorption; ABSORPTION PROPERTIES; COMPLEX PERMITTIVITY;
D O I
10.1016/j.physb.2009.06.065
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
NiZn- and NiCuZn-ferrite nanoparticles (50-70 nm) with the chemical formula Ni0.5Zn0.5Fe2O4 (NiZn) and Ni0.35Cu0.15Zn0.5Fe2O4 (NiCuZn) were synthesized by a combustion synthesis method. The nanocrystallite of these materials was characterized by structural and magnetic methods. Saturation magnetization increases from 83 emu/g (NiZn) to 91 emu/g (NiCuZn). Magnetic permeability and dielectric permittivity were measured on sintered samples (pellets and toroids) in the frequency range of 1 MHz-1.8 GHz. Reflection losses (R-L) for both samples were calculated from complex permeability and permittivity. Cu substitution in NiZn-ferrite enhances permeability and R-L. In order to explore microwave-absorbing proper-ties in X-band, magnetic nanoparticles were mixed with an epoxy resin to be converted into a microwave-absorbing composite and microwave behaviors of both materials were studied using a microwave vector network analyzer from 7.5 to 13.5 GHz. Cu substitution diminishes absorption intensity in the range 11.5-12.5 GHz. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:2713 / 2716
页数:4
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