Photoluminescence properties of SrZrO3:Eu3+ and BaZrO3:Eu3+ phosphors with perovskite structure

被引：87

作者：

Huang, Junli ^{[1
]}

Zhou, Liya ^{[1
]}

Wang, Zhengliang ^{[2
]}

Lan, Yuwei ^{[1
]}

Tong, Zhangfa ^{[1
]}

Gong, Fuzhong ^{[1
]}

Sun, Jianhua ^{[1
]}

Li, Liangping ^{[3
]}

机构：

[1] Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China

[2] Yunnan National Univ, Sch Chem & Biotechnol, Kunming 650031, Peoples R China

[3] Guangxi Univ, Sch Mech Engn, Nanning 530004, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2009年 / 487卷 / 1-2期

关键词：

Phosphors; Luminescence; Optical properties; LUMINESCENCE; NANOCRYSTALS; SOLUBILITY;

D O I：

10.1016/j.jallcom.2009.07.153

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sr1-xEuxZrO3 and BaZr1-xEuxO3 phosphors with different Eu3+-doped contents were synthesized by solid-state reaction. Their microstructure and photoluminescence properties were analyzed by X-ray techniques (XRD) and photoluminescence spectroscopy (PL), respectively. XRD results showed that SrZrO3:Eu3+ and BaZrO3:Eu3+ perovskites belonged to orthorhombic and cubic structure, respectively. PL spectra indicated that SrZrO3:Eu3+ emitted reddish-orange light and Eu3+ ions occupied two sites in SrZrO3 lattice; BaZrO3:Eu3+ emitted orange light and Eu3+ ions occupied one site in BaZrO3 lattice. In addition, the optimal Eu3+-doped contents of Sr1-xEuxZrO3 and BaZr1-xEuxO3 phosphors were both 3 mol%. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：L5 / L7

页数：3

共 15 条

[1] Rheological behaviour of BaZrO3 suspensions in non-aqueous media [J].

Boschini, F. ;

Rulmont, A. ;

Cloots, R. ;

Moreno, R. .

CERAMICS INTERNATIONAL, 2009, 35 (03) :1007-1013

[2] Photoluminescence properties of GdBa3B9O18:Ln3+ (Ln = Eu, Tb) under UV and VUV excitation [J].

Li, Xiao Xia ;

Wang, Yu Hua ;

Chen, Zhong .

JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 453 (1-2) :392-394

[3] Shape-controlled synthesis and characterization of BaZrO3 microcrystals [J].

Lu, ZG ;

Tang, YG ;

Chen, LM ;

Li, YD .

JOURNAL OF CRYSTAL GROWTH, 2004, 266 (04) :539-544

[4] Novel red phosphors for solid-state lighting:: the system NaM(WO4)2-x(MoO4)x:Eu3+ (M=Gd, Y, Bi) [J].

Neeraj, S ;

Kijima, N ;

Cheetham, AK .

CHEMICAL PHYSICS LETTERS, 2004, 387 (1-3) :2-6

[5] Local structure and thermal study of ytterbium-doped SrZrO3 [J].

Osaka, T ;

Numako, C ;

Koto, K .

MATERIALS RESEARCH BULLETIN, 1999, 34 (01) :11-24

[6] What makes the luminescence of Pr3+ different in CaTiO3 and CaZrO3? [J].

Pinel, E ;

Boutinaud, P ;

Mahiou, R .

JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 380 (1-2) :225-229

[7] Synthesis and optical characterization of SrHfO3:Ce and SrZrO3:Ce nanoparticles [J].

Retot, H. ;

Bessiere, A. ;

Kahn-Harari, A. ;

Viana, B. .

OPTICAL MATERIALS, 2008, 30 (07) :1109-1114

[8] Water vapor solubility and impedance of the high temperature proton conductor SrZr0.9Y0.1O2.95 [J].

Schober, T .

SOLID STATE IONICS, 2001, 145 (1-4) :319-324

[9] SOLUBILITY LIMIT OF LA IN SRZRO3 [J].

SURIYAYOTHIN, N ;

EROR, NG .

JOURNAL OF MATERIALS SCIENCE, 1984, 19 (09) :2775-2780

[10] Preparation and optical properties of trivalent europium doped into cordierite using the sol-gel process [J].

Thim, GP ;

Brito, HF ;

Silva, SA ;

Oliveira, MAS ;

Felinto, MCFC .

JOURNAL OF SOLID STATE CHEMISTRY, 2003, 171 (1-2) :375-381

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