Development of a Sila-Friedel-Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives

被引：205

作者：

Furukawa, Shunsuke ^{[1
]}

Kobayashi, Junji ^{[1
]}

Kawashima, Takayuki ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 40期

关键词：

ASYMMETRIC SPIROSILABIFLUORENE DERIVATIVES; PI-ELECTRON SYSTEMS; CRYSTAL-STRUCTURE; SILICON; CATION; CYCLIZATION; HYDROSILATION; SILYLATION; GENERATION; SUMANENE;

D O I：

10.1021/ja906566r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An intramolecular sila-Friedel-Crafts reaction was developed and applied to the synthesis of dibenzosilole derivatives. This reaction proceeds under mild conditions to afford the target in relatively high yield, indicating its availabilty as a versatile synthetic method. The synthesis of trisilasumanene, a silicon analogue of sumanene, was achieved using the present reaction.

引用

页码：14192 / +

页数：3

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