Acid/Base-Co-catalyzed Formal Baeyer-Villiger Oxidation Reaction of Ketones: Using Molecular Oxygen as the Oxidant

被引：21
作者：
Liu, Chun-Hua [1 ]
Wang, Zhuo [1 ]
Xiao, Li-Yun [1 ]
Mukadas [1 ]
Zhu, Dong-Sheng [1 ]
Zhao, Yu-Long [1 ]
机构：
[1] Northeast Normal Univ, Fac Chem, Jilin Prov Key Lab Organ Funct Mol Design & Synth, Changchun 130024, Jilin, Peoples R China
来源：
ORGANIC LETTERS | 2018年 / 20卷 / 16期
关键词：
CARBON-CARBON BOND; AMINE HYDROCHLORIDE SALTS; HYDROGEN-PEROXIDE; H FUNCTIONALIZATION; EFFICIENT SYNTHESIS; 3-SUBSTITUTED CYCLOBUTANONES; ALPHA-DIAZOCARBONYLS; SYNTHETIC APPROACH; COUPLING REAGENTS; AMIDE SYNTHESIS;
D O I：
10.1021/acs.orglett.8b02006
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel acid/base-co-catalyzed formal Baeyer-Villiger oxidation of various ketones using O-2 as the sole oxidant under metal-free conditions has been developed for the first time. The reaction tolerates a wide range of ketones and anilines and provides a simple and efficient method for the construction of various amides and isoquinolin-1-ones from the reactions of ketones with anilines in a single step.
引用
收藏
页码：4862 / 4866
页数：5
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