Acid/Base-Co-catalyzed Formal Baeyer-Villiger Oxidation Reaction of Ketones: Using Molecular Oxygen as the Oxidant

被引：23

作者：

Liu, Chun-Hua ^{[1
]}

Wang, Zhuo ^{[1
]}

Xiao, Li-Yun ^{[1
]}

Mukadas ^{[1
]}

Zhu, Dong-Sheng ^{[1
]}

Zhao, Yu-Long ^{[1
]}

机构：

[1] Northeast Normal Univ, Fac Chem, Jilin Prov Key Lab Organ Funct Mol Design & Synth, Changchun 130024, Jilin, Peoples R China

来源：

ORGANIC LETTERS | 2018年 / 20卷 / 16期

关键词：

CARBON-CARBON BOND; AMINE HYDROCHLORIDE SALTS; HYDROGEN-PEROXIDE; H FUNCTIONALIZATION; EFFICIENT SYNTHESIS; 3-SUBSTITUTED CYCLOBUTANONES; ALPHA-DIAZOCARBONYLS; SYNTHETIC APPROACH; COUPLING REAGENTS; AMIDE SYNTHESIS;

D O I：

10.1021/acs.orglett.8b02006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel acid/base-co-catalyzed formal Baeyer-Villiger oxidation of various ketones using O-2 as the sole oxidant under metal-free conditions has been developed for the first time. The reaction tolerates a wide range of ketones and anilines and provides a simple and efficient method for the construction of various amides and isoquinolin-1-ones from the reactions of ketones with anilines in a single step.

引用

页码：4862 / 4866

页数：5

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