Pyrite from coal mining: High-energy milling and analysis of the electrical and optical properties

Pyrite is part of the tailings from coal mining and presents a great valorization potential technological, economic and environmental in the production of nanoparticles. In this work, pyrite from coal mining was subjected to high-energy milling and the particle size reduction, electrical and optical properties were evaluated. With the milling parameters used, the apparent size of the crystallites was reduced from 34.7 nm to 23.8 nm, resulting in highly unstable particles and charge carriers with low mobility. Due to this instability, submicron particles were observed, in the range of 300-500 nm, with a hydrodynamic diameter of 1257 +/- 36 nm. The processed pyrite showed good visible light absorption and an indirect band gap of 1.51 eV. (C) 2019 Elsevier B.V. All rights reserved.