CuO-catalyzed oxidation of aryl acetates with aqueous tert-butyl hydroperoxide for the synthesis of α-ketoesters

被引：2

作者：

Jiang, Jin ^{[1
]}

机构：

[1] Sichuan Univ Sci & Engn, Sch Chem & Environm Engn, Zigong 643000, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2019年 / 43卷 / 7-8期

关键词：

aryl acetates; CuO; alpha-ketoesters; oxidation; tert-butyl hydroperoxide; KETO ESTERS; ALKYLBENZENES; KETOAMIDES;

D O I：

10.1177/1747519819861317

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A practical method to access alpha-ketoesters from readily available aryl acetates is developed. In this approach, aqueous tert-butyl hydroperoxide and CuO are employed. No additional solvents are required and it was found that the peroxide side products in the reaction can be decomposed by pyridine.

引用

页码：235 / 240

页数：6

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