Solvothermal synthesis of [Mn(en)(3)](2)[Mn-4(en)(9)(SbSe4)(4)]center dot 2H2O: the first example of a selenoantimonate(v) acting as a ligand in a transition-metal complex

被引：63

作者：

Bensch, W

Nather, C

Schur, M

机构：

[1] Inst. für Anorganische Chemie, Universität Kiel, D-24098-Kiel

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a702844j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of elemental manganese, antimony and selenium under mild solvothermal conditions yields the complex anion [Mn-4(en)(9)(SbSe4)(4)](4-), the first example of a transition-metal complex with SbSe43- anions acting as ligands; the anions are coordinated in a terminal position as well as a bridging ligand.

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页码：1773 / 1774

页数：2

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