Model for the Thermodynamic Properties of a Biodiesel Fuel

被引：102

作者：

Huber, Marcia L. ^{[1
]}

Lemmon, Eric W. ^{[1
]}

Kazakov, Andrei ^{[1
]}

Ou, Lisa S. ^{[1
]}

Bruno, Thomas J. ^{[1
]}

机构：

[1] Natl Inst Stand & Technol, Thermophys Properties Div, Boulder, CO USA

来源：

ENERGY & FUELS | 2009年 / 23卷 / 07期

关键词：

ACID METHYL-ESTERS; DISTILLATION CURVES; PHYSICAL-PROPERTIES; VAPOR-PRESSURES; LIQUID-EQUILIBRIA; FATTY; IMPROVEMENTS; PALMITATE; EQUATIONS; STATE;

D O I：

10.1021/ef900159g

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

We present an equation-of-state approach to modeling the thermodynamic properties of a biodiesel fuel. Preliminary Helmholtz-type equations of state were developed with limited experimental data for live fatty acid methyl esters (FAMEs) that are the primary constituents of soy-based biodiesel fuel, namely, methyl palmitate, methyl stearate, methyl oleate, methyl linoleate, and methyl linolenate. These components Were combined in a mixture model using ideal mixing to represent the thermodynamic properties of a biodiesel fuel. We performed limited experimental measurements on the density, sound speed. and initial boiling point of two biodiesel fuel samples and compared the results with the model.

引用

页码：3790 / 3797

页数：8